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Structure, valence state and magnetic properties of LnGA_(1-x)V_xO_3

机译:LnGA_(1-x)V_xO_3的结构,价态和磁性能

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摘要

Recently considerable attention has been paid to the ABO_3 type RE complex oxides since they have special electrical-magnetic properties, good catalytic behaviour and gas sensitive behaviour. One of them is ABO_3 type RE gallate system, which has somecharacteristic luminescent properties. Vanadium is one of the transition elements with wide application. But LnGa_(1_x)V_xO_3 has not been reported in literature; so the valence state of vanadium ions and the substitution effect of vanadium for galliumon the structure and magnetic properties of these compounds are studied in this note and then the correlation regularities between neighbouring environments of RE elements and properties of compounds are investigated.
机译:最近,由于ABO_3型RE复合氧化物具有特殊的电磁特性,良好的催化性能和对气体敏感的性能,因此引起了人们的广泛关注。其中之一是ABO_3型RE没食子酸酯系统,该系统具有某些特征的发光特性。钒是具有广泛应用的过渡元素之一。但是,文献中尚未报道LnGa_(1_x)V_xO_3。因此,本文研究了钒离子的价态以及钒对镓的取代作用对这些化合物的结构和磁性能的影响,然后研究了稀土元素周围环境与化合物性能之间的相关性规律。

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