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Investigation of novel tri-functional epoxy resin derived from cardanol as partial replacement of BPA based epoxy in zinc rich primer

机译:腰果酚衍生的新型三官能团环氧树脂在富锌底漆中部分取代BPA基环氧树脂的研究

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摘要

Purpose - The purpose of this paper is to explore the application of triglycidyl resin (TGC) prepared from cardanol as partial replacement of conventional bis-phenol A (BPA) based epoxy resin for zinc rich primers (ZRPs). Design/methodology/approach - The synthesis of new platform chemicals that are based on renewable resources has been accepted as a strategy to contribute to sustainable development due to the anticipated depletion of fossil oil reserves and rising oil prices. We prepared a tri-functional epoxy resin from cardanol which can be used as partial replacement of BPA based epoxy. The ZRPs were prepared using 50:50 ratio of TGCBPA epoxy, and the coatings were evaluated for mechanical, chemical and anticorrosive properties. Findings - The 50 per cent replacement of BPA based epoxy by TGC resulted in at par mechanical, chemical and anticorrosive properties as evaluated by various methods. The successful implementation can thus contribute to sustainable development by "green chemistry" route. Research limitations/implications - The prepared TGC resin in the current work was studied for application in ZRPs. This can also be explored for high performance coatings, adhesives and other engineering applications. Practical implications - The TGC binder was prepared by simple two-step reaction. This can successfully be used as binder for coating application without any modifications. Originality/value - A novel approach of using green and ecofriendly TGC resin as replacement of high cost BPA based epoxy was explored and can be implemented for numerous applications.
机译:目的-本文的目的是探讨由腰果酚制得的三缩水甘油基树脂(TGC)的应用,以代替传统的基于双酚A(BPA)的环氧树脂作为富锌底漆(ZRP)的一部分。设计/方法/方法-由于预计化石石油储量的枯竭和油价上涨,基于可再生资源的新平台化学品的合成已被视为有助于可持续发展的战略。我们从腰果酚制备了一种三官能环氧树脂,可用作部分替代基于BPA的环氧树脂。使用TGCBPA环氧树脂比例为50:50制备ZRP,并评估涂料的机械,化学和防腐性能。研究结果-经各种方法评估,TGC可以将BPA基环氧树脂替代50%,从而获得同等的机械,化学和防腐性能。因此,成功的实施可以通过“绿色化学”路线为可持续发展做出贡献。研究局限/意义-研究了当前工作中制备的TGC树脂在ZRP中的应用。对于高性能涂料,粘合剂和其他工程应用,也可以进行探索。实际意义-通过简单的两步反应制备TGC粘合剂。无需做任何改动,就可以成功地用作涂料的粘合剂。原创性/价值-探索了一种使用绿色环保TGC树脂替代高成本BPA基环氧树脂的新颖方法,该方法可用于众多应用。

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