Synthesis and crystal structure of trinuclear Fe carbonyl cluster Fe_3(CO)_8S_2CNC_6H_5

XU Jichun; JIAO Fengying; YIN Yuanqi

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Synthesis and crystal structure of trinuclear Fe carbonyl cluster Fe_3(CO)_8S_2CNC_6H_5

机译：三核Fe羰基簇Fe_3（CO）_8S_2CNC_6H_5的合成及晶体结构

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Metal cluster chemistry is an active studying field nowadays, It is possible that metal clusters can be developed as new homogeneous catalysts with special functions. Organoiron clusters, which could be easily synthesized at lowei price, are very important in metal cluster chemistry, Fe_3(CO)_(12) is a very useful compound with higher activity than Fe(CO)_5 in the syntheses of carbonyliron clusters. Fe_3(CO)_9S_2 compound is the main product in the reaction of Fe_3(CO)_(12) with organic sulfide. In ref, [3], the reaction of Fe_3(CO)_(12) with NH_4CNS was carried out to yield Fe_3(CO)_9S_2 too, which clearly shows the sulfidophilic action of Fe_3(CO)_(12).

机译：金属团簇化学是当今一个活跃的研究领域，有可能将金属团簇开发为具有特殊功能的新型均相催化剂。有机铁簇很容易以低价合成，在金属簇化学中非常重要，Fe_3（CO）_（12）是一种非常有用的化合物，在羰基铁簇的合成中比Fe（CO）_5具有更高的活性。 Fe_3（CO）_（9S_2）是Fe_3（CO）_（12）与有机硫化物反应的主要产物。在参考文献[3]中，也进行了Fe_3（CO）_（12）与NH_4CNS的反应，得到Fe_3（CO）_9S_2，这清楚地表明了Fe_3（CO）_（12）的硫化作用。

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来源
《Chinese science bulletin》 |1995年第2期|共4页
作者
XU Jichun; JIAO Fengying; YIN Yuanqi;
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正文语种 eng
中图分类自然科学现状及发展;
关键词
trinuclear iron cluster; transition metal compound; crystal structure;

机译：三核铁簇;过渡金属化合物;晶体结构;

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专利

1. Synthesis and crystal structure of trinuclear Fe carbonyl cluster Fe_3(CO)_8S_2CNC_6H_5 [J] . XU Jichun, JIAO Fengying, YIN Yuanqi Chinese science bulletin . 1995,第2期

机译：三核Fe羰基簇Fe_3（CO）_8S_2CNC_6H_5的合成及晶体结构
2. Remarkable Aspects of Unsaturation in Trinuclear Metal Carbonyl Clusters:The Triiron Species Fe_3(CO)_n (n=12,11,10,9) [J] . Hongyan Wang, Yaoming Xie, R.Bruce King Journal of the American Chemical Society . 2006,第35期

机译：三核金属羰基簇中不饱和度的显着方面：三铁物种Fe_3（CO）_n（n = 12,11,10,9）
3. Effect of Hydrogen Atoms on the Structures of Trinuclear Metal Carbonyl Clusters: Trinuclear Manganese Carbonyl Hydrides [J] . Liu XM, Wang CY, Lu QS, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第10期

机译：氢原子对三核金属羰基簇结构的影响：三核锰羰基氢化物
4. Synthesis and Crystal Structure of Dinuclear Iron Carbonyl Cluster Containing a Phosphido-Thiolato Bridging Ligand [C] . Bingfang Wu 11th International Symposium of Fine Chemistry and Functional Polymers Jul 28-31, 2001 Hailar, Inner Mongolia, P.R. China . 2001

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6. Synthesis Crystal Structure of a New Triosmium Alkylidyne Carbonyl Cluster Containing a Chiral Ferrocenylphosphine Ligand [O] . Wai-Yeung Wong 2005

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8. 'Clustered Cluster' with a 'Pinwheel' Ligand Array. Synthesis and Structure of a Trinuclear Cupracarborane [R] . Kang, H. C., Do, Y., Knobler, C. B., 1989

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Synthesis and crystal structure of trinuclear Fe carbonyl cluster Fe_3(CO)_8S_2CNC_6H_5

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