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CuS-poly (N-isopropylacryl-amide-co-acrylic acid) composite microspheres with patterned surface structures: preparation and characterization

机译:具有图案化表面结构的CuS-聚(N-异丙基丙烯酰胺-共丙烯酸)复合微球:制备与表征

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摘要

N-isopropylacrylamide (NIPAM) and acrylic acid (AA) copolymer microspheres with various compositions were prepared by reverse suspension polymerization technique. The microspheres thus prepared were employed as micro-reactors for the deposition of CuS. In this way, several CuS-P(NIPAM-co-AA) composite microspheres with different surface morphologies were prepared. It was demonstrated that the surface structures of the composite microspheres can be tailored to a certain extent by varying the ratio ofthe two monomer units in the template (microgels) and/or the amount of CuS deposited. It is in prospect that the inherent advantages of microgel templates (the size, composition, charge nature and density, and crosslinking density could be easily controlled) would make the microgel template method extremely useful in the preparation of composite microspheres with different patterned surface structures.
机译:采用反向悬浮聚合技术制备了具有不同组成的N-异丙基丙烯酰胺(NIPAM)和丙烯酸(AA)共聚物微球。如此制备的微球被用作微反应器用于CuS的沉积。以这种方式,制备了具有不同表面形态的几个CuS-P(NIPAM-co-AA)复合微球。结果表明,通过改变模板(微凝胶)中两种单体单元的比例和/或沉积的CuS量,可以在一定程度上调整复合微球的表面结构。可以预见的是,微凝胶模板的固有优势(尺寸,组成,电荷性质和密度以及交联密度可以轻松控制)将使微凝胶模板方法在制备具有不同图案表面结构的复合微球中极为有用。

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