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Non-equilibrium phase diagram of stationary states for low-pressure diamond growth

机译:低压金刚石生长的稳态非平衡相图

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摘要

Now, it is well known that stable diamond growth and etching of graphite can be realized simultaneously under low pressures, but it is difficult to explain by classical thermodynamics. Based on the non-equilibrium thermodynamic coupling theorem, low-pressure diamond growth can be explained clearly as follows: The change of Gibbs free energy (G) is the criterion of reaction direction at constant temperature and pressure.
机译:现在,众所周知,可以在低压下同时实现稳定的金刚石生长和石墨腐蚀,但是很难用经典的热力学来解释。基于非平衡热力学耦合定理,可以清楚地解释低压金刚石的生长:吉布斯自由能(G)的变化是在恒定温度和压力下反应方向的判据。

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