The influence of the organic substituents from the polyhedral oligomeric silsesquioxane (POSS) cage on the epoxy-POSS hybrid materials properties

FLORIANA CONSTANTIN; SORINA ALEXANDRA GAREA; GEORGETA VOICU

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The influence of the organic substituents from the polyhedral oligomeric silsesquioxane (POSS) cage on the epoxy-POSS hybrid materials properties

机译：多面体低聚倍半硅氧烷（POSS）笼中有机取代基对环氧-POSS杂化材料性能的影响

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This paper reports the synthesis of new reinforcing agents based on sodium montmorillonite modified with some polyhedral oligomeric silsesquioxanes. The modified montmorillonite was extensively characterized using different techniques such as Fourier transform infrared spectroscopy, thermo-gravimetric analysis, X-ray diffraction and X-ray photoemission spectroscopy. The obtained reinforcing agents were used for the synthesis of epoxy-based nanocomposites. The nanocomposites were studied using thermal analysis, dynamic mechanical analysis, differential scanning calorimetry and thermogravi-metric analysis to conclude that the type of radicals on the POSS cage may influence the properties of the final nanocomposites.

机译：本文报道了基于蒙脱土钠的多面体低聚倍半硅氧烷改性的新型增强剂的合成。使用诸如傅里叶变换红外光谱，热重分析，X射线衍射和X射线光发射光谱等不同技术对改性蒙脱土进行了广泛表征。所获得的增强剂用于合成环氧基纳米复合材料。使用热分析，动态力学分析，差示扫描量热法和热重分析法研究了纳米复合材料，得出的结论是，POSS笼上自由基的类型可能会影响最终纳米复合材料的性能。

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来源
《High performance polymers》 |2010年第8期|共11页
作者
FLORIANA CONSTANTIN; SORINA ALEXANDRA GAREA; GEORGETA VOICU;
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正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
Polyhedral oligomeric silsesquioxane; montmorillonite; hybrid materials; epoxy resin;

机译：多面体低聚倍半硅氧烷;蒙脱土;混合材料;环氧树脂;

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1. The influence of the organic substituents from the polyhedral oligomeric silsesquioxane (POSS) cage on the epoxy-POSS hybrid materials properties [J] . FLORIANA CONSTANTIN, SORINA ALEXANDRA GAREA, GEORGETA VOICU High performance polymers . 2010,第8期

机译：多面体低聚倍半硅氧烷（POSS）笼中有机取代基对环氧-POSS杂化材料性能的影响
2. Influence of n-alkyl substituents on the thermal behaviour of Polyhedral Oligomeric Silsesquioxanes (POSSs) with different cage's periphery [J] . Blanco I., Bottino F. A., Abate L. Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems . 2016,第Null期

机译：n-烷基取代基对不同笼型外围多面体低聚倍半硅氧烷（POSSs）热行为的影响
3. SYNTHESIS AND CHARACTERIZATION OF ORGANIC/INORGANIC HYBRID MATERIALS BASED ON POLYHEDRAL OLIGOMERIC SILSESQUIOXANE (POSS) AND POLY(ETHYLENE GLYCOL) VIA CLICK CHEMISTRY [J] . Ghodsi MOHAMMADI ZIARANI, Shima ASADI, Alireza BADIEI, Revue roumaine de chimie . 2019,第5期

机译：基于多化学低聚倍半硅氧烷（POSS）和聚（乙二醇）的有机/无机杂化材料的合成与表征
4. Preparation and properties of cage-like octaaminopropyl polyhedral oligomeric silsesquioxane/polyvinyl alcohol hybrid materials [C] . Xiaojing Zhang, Chaojun Wang, Jiashu Sun International Conference on Chemical Engineering and Advanced Materials . 2011

机译：笼状八氨基丙基多面体低聚硅氧烷喹甲酸/聚乙烯醇杂交材料的制备及性能
5. Electronic Properties and Charge Transport of Polyhedral Oligomeric Silsesquioxanes (POSS) Derivatives and Materials Design for Highly Efficient Organic Light Emitting Diodes. [D] . Zhen, Changgua. 2011

机译：多面体低聚倍半硅氧烷（POSS）衍生物的电子性能和电荷传输以及高效有机发光二极管的材料设计。
6. Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO [O] . Mohamed Gamal Mohamed, Mei-Yin Tsai, Chih-Feng Wang, 2021

机译：多功能多面体低聚倍半硅氧烷（POSS）基于CO的杂种多孔材料
7. Phenyl hepta cyclopentyl-polyhedral oligomeric silsesquioxane (ph,hcp-POSS)/Polystyrene (PS) nanocomposites: the influence of substituents in the phenyl group on the thermal stability [O] . I. Blanco, L. Abate, Marta Letizia Antonelli, 2012

机译：苯基七环戊基多面体低聚倍半硅氧烷（ph，hcp-POSS）/聚苯乙烯（PS）纳米复合材料：苯基中取代基对热稳定性的影响
8. Hybrid Inorganic-Organic Performance Fluids Based on Polyhedral Oligomeric Silsesquioxanes (POSS) [R] . Blanski, R. , Leland, J. , Viers, B. , 2002

机译：基于多面体低聚倍半硅氧烷（pOss）的混合无机 - 有机高性能流体

The influence of the organic substituents from the polyhedral oligomeric silsesquioxane (POSS) cage on the epoxy-POSS hybrid materials properties

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