Kinetic studies of gold(III) chloride complex reduction and solid phase precipitation in acidic aqueous system using dimethylamine borane as reducing agent

Marek Wojnicki; Ewa Rudnik; Magdalena Luty-Blocho

首页> 外文期刊>Hydrometallurgy >Kinetic studies of gold(III) chloride complex reduction and solid phase precipitation in acidic aqueous system using dimethylamine borane as reducing agent

【24h】

Kinetic studies of gold(III) chloride complex reduction and solid phase precipitation in acidic aqueous system using dimethylamine borane as reducing agent

机译：以二甲胺硼烷为还原剂的酸性水体系中氯化金（III）配合物还原和固相沉淀的动力学研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Kinetics of gold(III) chloride complex ions reduction with dimethylamine borane and precipitation of gold nanoparticles was investigated. The influence of concentrations of reductant, gold(III) chloride complex ions, neutral salt and chloride ions as well as temperature on the process was reported. Experimental results were used to determine parameters in the Arrhenius equation. A set of reactions occurring in the system was proposed. Rate equations were presented and verified. It was proposed that state of the catalytic surface of gold particles play a crucial role in the mechanism of the reaction and competition between AuCl_4~- adsorption and AuCl_4~- reduction on the metal particles exists in the system. Microscopic observations as well as analysis of the particles were also performed.

机译：研究了二甲胺硼烷还原氯化金（III）络合物离子的动力学以及金纳米颗粒的沉淀。报道了还原剂，氯化金（III）络合物离子，中性盐和氯离子的浓度以及温度对工艺的影响。实验结果用于确定Arrhenius方程中的参数。提出了在系统中发生的一组反应。提出并验证了速率方程。有人认为，金颗粒催化表面的状态在反应机理中起着至关重要的作用，并且系统中存在金颗粒吸附AuCl_4〜-和AuCl_4〜-还原之间的竞争。还进行了显微镜观察以及颗粒分析。

著录项

来源
《Hydrometallurgy》 |2012年第null期|共11页
作者
Marek Wojnicki; Ewa Rudnik; Magdalena Luty-Blocho;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类冶金技术;
关键词
Gold recovery; Kinetics; Reduction; Metal precipitation; DMAB;

机译：金回收;动力学;还原;金属沉淀;DMAB;

相似文献

外文文献
中文文献
专利

1. Kinetic studies of gold(III) chloride complex reduction and solid phase precipitation in acidic aqueous system using dimethylamine borane as reducing agent [J] . Marek Wojnicki, Ewa Rudnik, Magdalena Luty-Blocho Hydrometallurgy . 2012,第Null期

机译：以二甲胺硼烷为还原剂的酸性水体系中氯化金（III）配合物还原和固相沉淀的动力学研究
2. The kinetic studies of gold(III) chloride complex adsorption mechanism from an aqueous and semi-aqueous system [J] . Wojnicki Marek, Luty-Blocho Magdalena, Socha Robert P., Journal of Molecular Liquids . 2019,第期

机译：金（III）金（III）氯化物复合吸附机理的动力学研究来自水性和半水体系
3. Gold nanoparticles formation in the aqueous system of gold(III) chloride complex ions and hydrazine sulfate-Kinetic studies [J] . Streszewski B., Jaworski W., Pac?awski K., Colloids and Surfaces, A. Physicochemical and Engineering Aspects . 2012,第Null期

机译：氯化金（III）络合物离子和硫酸肼在水体系中金纳米颗粒的形成-动力学研究
4. Oxidation of aniline and its derivatives by tert-butylhydroperoxide using meso-tetraphenylporphyriniron(iii) chloride as catalyst in aqueous acetic acid medium: Degradation kinetics [C] . R. Mayildurai, M. Raja, V. Akhileshuvar International Conference on Physics and Chemistry of Materials in Novel Engineering Applications . 2020

机译：使用Meso-Tetraphynylyriniron（III）作为乙酸水溶液中催化剂的叔丁基氧化盐氧化苯胺及其衍生物的氧化：降解动力学
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. Reductive Precipitation of Gold by Dissimilatory Fe(III)-Reducing Bacteria and Archaea [O] . Kazem Kashefi, Jason M. Tor, Kelly P. Nevin, 2001

机译：异化还原Fe（III）细菌和古细菌对金的还原沉淀
7. Amineanionogold(III) Complexes. V. Kinetics of the Consecutive Substitutions of Ammonia by Chloride in Tetraamminegold(III) Ion in Acidic Aqueous Solution. [O] . J. Ventegodt, Bodil Øby, L. H. Skibsted, 1985

机译：Amineanionogold（III）复合物。 V.在酸性水溶液中氯化物中氯化物连续取代氨的动力学。

Kinetic studies of gold(III) chloride complex reduction and solid phase precipitation in acidic aqueous system using dimethylamine borane as reducing agent

摘要

著录项

相似文献

相关主题

期刊订阅