The influence of the treatment of Zr(IV) and Hf(IV) sulfate solution on the ion-exchange purifying of zirconium from hafnium on Diphonix? resin

Agata Jakobik-Kolon; Marek Smolik; Hanna Jaroszek

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The influence of the treatment of Zr(IV) and Hf(IV) sulfate solution on the ion-exchange purifying of zirconium from hafnium on Diphonix? resin

机译：Zr（IV）和Hf（IV）硫酸盐溶液的处理对Di在Diphonix上离子交换纯化锆的影响。树脂

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The tendency of Zr( IV) and Hf(FV) to form polynuclear species (especially mixed Zr-O-Hf complexes) in aqueous solutions is, besides their almost identical chemical properties, one of the main obstacles in their separation. Therefore, finding a suitable way for the aforementioned complexes to decompose may play a crucial role in efficiently purifying zirconium from hafnium. The best purifying efficiency on Diphonix~R resin was obtained with a zirconium sulfate solution prepared with the intermediate stage of fluoride complexes creation. This permits the collection of the purest fraction of the zirconium sulfate solution, which has a hafnium content ten times lower than in the case of typically prepared solutions.

机译：Zr（IV）和Hf（FV）在水溶液中形成多核物种（尤其是混合的Zr-O-Hf配合物）的趋势，除了它们几乎相同的化学性质外，也是分离它们的主要障碍之一。因此，找到合适的方法使上述配合物分解可能对从ha中有效纯化锆起关键作用。用生成氟化物配合物的中间阶段制备的硫酸锆溶液可获得对Diphonix®R树脂的最佳纯化效率。这允许收集最纯净的硫酸锆溶液馏分，其sulfate含量比通常制备的溶液低十倍。

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《Hydrometallurgy》 |2013年第null期|共5页
作者
Agata Jakobik-Kolon; Marek Smolik; Hanna Jaroszek;
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正文语种 eng
中图分类冶金技术;
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Hafnium removal from zirconium; Ion-exchange; Hafnium and zirconium aqueous solutions;

机译：从锆中去除;离子交换;H和锆水溶液;

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1. 锻造工艺对Ti-6．5Al-1Mo-IV-2Zr合金大规格棒材的组织与性能的影响 [J] . 黄德明, 王怀柳, 陈鑫, 中国有色金属学报：英文版 . 2013,第008期
2. The influence of the treatment of Zr(IV) and Hf(IV) sulfate solution on the ion-exchange purifying of zirconium from hafnium on Diphonix? resin [J] . Agata Jakobik-Kolon, Marek Smolik, Hanna Jaroszek Hydrometallurgy . 2013,第Null期

机译：Zr（IV）和Hf（IV）硫酸盐溶液的处理对Di在Diphonix上离子交换纯化锆的影响。树脂
3. Trimethylphosphine halide complexes of titanium, zirconium and hafnium in oxidation states IV, III and II. Crystal structure of MI4(PMe3)(n) (M=Zr, n=3; M=Hf, n=2.5), M2X6(PMe3)(4) (M=Hf, Ti, X=1; M=Zr, X=Br) and (mu-eta(6),eta(6)-C6H6)Hf2I4-(PMe3)(4 [J] . Troyanov SI., Teuben JH., Meetsma A. Inorganica Chimica Acta . 1998,第1a2期

机译：钛，锆和ha的三甲基膦卤化物络合物，氧化态为IV，III和II。 MI4（PMe3）（n）（M = Zr，n = 3; M = Hf，n = 2.5），M2X6（PMe3）（4）（M = Hf，Ti，X = 1; M = Zr， X = Br）和（mu-eta（6），eta（6）-C6H6）Hf2I4-（PMe3）（4
4. 2:2-Type complexes of zirconium(IV)/hafnium(IV) centers with mono-lacunary Keggin polyoxometalates: Syntheses and molecular structures of [(a-SiW_(11)O_(39)M)_2(μ-OH)_2]~(10-) (M = Zr, Hf) with edge-sharing octahedral units and [(a-SiW_(11)O_(39)M)_2(μ-OH)_3]~(11-) with face-sharing octahedral units [J] . Hironori Osada, Akio Ishikawa, Yoshio Saku, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第Null期

机译：锆（IV）/ ha（IV）中心与单腔Keggin多金属氧酸盐的2：2-型配合物：[（a-SiW_（11）O_（39）M）_2（μ-OH）_2的合成和分子结构]〜（10-）（M = Zr，Hf）的边缘共享八面体单元和[（a-SiW_（11）O_（39）M）_2（μ-OH）_3]〜（11-）的表面共享八面体单位
5. Hafnium (IV) and zirconium (IV) porphyrinoid diacetate complexes as new dyes for solar cells [C] . Radivojevic Ivana, Sfeir Matthew, Nam Chang-Yong, 35th IEEE Photovoltaic Specialists Conference . 2010

机译：por（IV）和锆（IV）卟啉类双乙酸盐络合物作为太阳能电池的新染料
6. Zirconium(IV) and Hafnium(IV) Porphyrin and Phthalocyanine Complexes as New Dyes for Solar Cell Devices [O] . Ivana Radivojevic, Giorgio Bazzan, Benjamin P. Burton-Pye, -1

机译：锆（IV）和铪（IV）卟啉和酞菁配合物作为太阳能电池装置的新染料
7. An X-Ray Investigation of Some Aqueous Zirconium(IV) Halide, a Hafnium(IV) Chloride, and Some Zirconium(IV) Perchlorate Solutions. [O] . Märtha Åberg, Sigrid Furuseth, Kari Selte, 1977

机译：对一些锆（IV）卤化物，铪（IV）氯化物和一些锆（IV）高氯酸盐溶液的X射线研究。
8. Reprocessing cruds: zirconium (IV) contribution to their formation dibutylphosphoric acid demixion induced by zirconium (IV) in nitric acid solutions. Solubility of zirconium (IV) in HDBP [R] . Livet, J. , Berthon, C. 1994

机译：再加工粗泥：锆（IV）在硝酸溶液中由锆（IV）诱导形成二丁基磷酸分层。锆（IV）在HDBp中的溶解度

The influence of the treatment of Zr(IV) and Hf(IV) sulfate solution on the ion-exchange purifying of zirconium from hafnium on Diphonix? resin

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