A cyclic Hydroxylaminato-aminoxide complex of gallium

B?sing P.; Neumann B.; Stammler H.-G.; Mitzel N.W.

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A cyclic Hydroxylaminato-aminoxide complex of gallium

机译：镓的环状羟丙氨酰胺复合物

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The reaction of HON(tBu)CH_2CH_2N(tBu)OH with tri-terf-butyl gallium affords a hydroxylaminato complex of the formula [tBu_2Ga{ON(tBu)CH_2CH_2N(H)(tBu)O}], which contains a monoanionic bishydroxylaminato ligand with one anionic and one neutral, but tautomeric aminoxide end, both linked to gallium by their oxygen atoms leading to a seven-membered ring. The compound was characterised by elemental analysis, 1H and 13C NMR and determination of its crystal structure.

机译：HON（tBu）CH_2CH_2N（tBu）OH与三叔丁基镓的反应得到式[tBu_2Ga {ON（tBu）CH_2CH_2N_2（H）（tBu）O}]的羟基氨基配合物，其中含有单阴离子双羟基laminato配体具有一个阴离子和一个中性但互变异构的氨氧化物末端，两者均通过其氧原子与镓连接，从而形成一个七元环。该化合物通过元素分析，1 H和13 C NMR并测定其晶体结构进行表征。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第15期|共3页
作者
B?sing P.; Neumann B.; Stammler H.-G.; Mitzel N.W.;
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正文语种 eng
中图分类化学;
关键词
Aminoxides; Gallium; Hydroxylamine; N; O ligands; X-ray diffraction;

机译：氨基氧化物;镓;羟胺;N;O配体;X射线衍射;

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专利

1. A cyclic Hydroxylaminato-aminoxide complex of gallium [J] . B?sing P., Neumann B., Stammler H.-G., Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第15期

机译：镓的环状羟丙氨酰胺复合物
2. Synthesis and structural characterization of various N,O,N-chelated aluminum and gallium complexes for the efficient ROP of cyclic esters and carbonates: How do aluminum and gallium derivatives compare ? [J] . Hild F., Neehaul N., Bier F., Organometallics . 2013,第2期

机译：各种N，O，N螯合的铝和镓络合物的合成和结构表征，可有效提高环酯和碳酸盐的ROP：铝和镓衍生物如何比较？
3. Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates [J] . SamuelDagorne, Mickael Normand, Evgeny Kirillov, Coordination chemistry reviews . 2013,第11a12期

机译：镓和铟配合物，用于环状醚，酯和碳酸酯的开环聚合
4. EVALUATION OF CYCLIC GALLIUM AMIDES AS PRECURSORS FOR GALLIUM NITRIDE THIN FILMS [C] . Jayaprakash Khanderi, Manuela Winter, Harish Parala, Proceedings vol.2005-09; European Conference on Chemical Vapor Deposition(EURCVD-15); 20050905-09; Bochum(DE) . 2005

机译：循环镓酰胺作为氮化镓薄膜前兆的评估
5. Metal ion complexation by acyclic and cyclic multidentate ligands. [D] . Elkarim, Nazar Saied Awad. 1999

机译：金属离子通过无环和环状多齿配体络合。
6. Metal-Polymer Complexes of Gallium/Gallium-68 with Copolymers of N-Vinylpyrrolidonewith N-Vinylformamideand N-Vinyliminodiacetic Acid: A Hint for Radiolabeling of Water-Soluble Synthetic Flexible Chain Macromolecules [O] . Nikolay I. Gorshkov, Аndrey Yu. Murko, Iirina I. Gavrilova, 2020

机译：镓/镓-68的金属聚合物配合物具有N-乙烯基吡咯烷酮的共聚物N-乙烯基甲基胺基乙烯基二乙酰乙酸：一种用于水溶性合成柔性链大分子的放射性标记的提示
7. Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates [O] . Dagorne, Samuel, Normand, Mickaël, Kirillov, Evgeny, 2013

机译：镓和铟配合物，用于环状醚，酯和碳酸酯的开环聚合

A cyclic Hydroxylaminato-aminoxide complex of gallium

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