Two- and three-dimensional hybrid compounds formed by 1,2-, 1,3- and 1,4-cyclohexanedicarboxylates of zinc

Matte H.S.S.R.; Swain S.K.; Thirumunigan A.; Rao C.N.R.

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Two- and three-dimensional hybrid compounds formed by 1,2-, 1,3- and 1,4-cyclohexanedicarboxylates of zinc

机译：由锌的1,2-，1,3-和1,4-环己烷二羧酸盐形成的二维和三维杂化化合物

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By employing the hydrothermal method, five zinc cyclohexanedicarboxylates (CHDCs) with the compositions, [Zn_2(1,4-CHDC)-(1,10-phen) _4]·(H_2O)_2(NO_3)_2 (I), [Zn(1,4-CHDC)] (II), [Zn_3(1,3-CHDC)_3(4,4′-bipy) ] (III), [Zn_5(OH)_2(1,3-CHDC)_4] (IV), and [Zn(1,2-CHDC)] (V), were prepared, and characterised. Compound I is a molecular structure while II, III and V have two-dimensional layered structures. Compounds II, III and V are coordination polymers (I~0O~2) possessing zero-dimensional inorganic connectivity (I~n, n = 0) and two-dimensional organic connectivity (O~m, m = 2). Compound IV is a coordination polymer (I~0O~3) possessing zero-dimensional inorganic connectivity (I~n, n = 0) and three-dimensional organic connectivity (O~m, m = 3). In all these compounds, the CHDC anions are in the (e,e) conformation except in II, where it has the (a,e) conformation.

机译：通过水热法，五种环己烷二甲酸锌（CHDC）的组成为[Zn_2（1,4-CHDC）-（1,10-phen）_4]·（H_2O）_2（NO_3）_2（I），[Zn （1,4-CHDC）]（II），[Zn_3（1,3-CHDC）_3（4,4'-bipy）]（III），[Zn_5（OH）_2（1,3-CHDC）_4]制备（IV）和[Zn（1,2-CHDC）]（V）并进行表征。化合物I是分子结构，而II，III和V具有二维分层结构。化合物II，III和V是配位聚合物（I〜0O〜2），具有零维无机连接性（I〜n，n = 0）和二维有机连接性（O〜m，m = 2）。化合物IV为配位聚合物（I〜0O〜3），具有零维无机连接性（I〜n，n = 0）和三维有机连接性（O〜m，m = 3）。在所有这些化合物中，CHDC阴离子均具有（e，e）构象，但II中的CHDC阴离子具有（a，e）构象。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第12期|共8页
作者
Matte H.S.S.R.; Swain S.K.; Thirumunigan A.; Rao C.N.R.;
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正文语种 eng
中图分类化学;
关键词
Carboxylate ligands; Cyclohexanedicarboxylates; Hybrid compounds; Hydrothermal synthesis; Structure elucidation; Zinc cyclohexanedicarboxylates;

机译：羧酸盐配体;环己二羧酸盐;杂化化合物;水热合成;结构解析;环己二羧酸锌;

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1. Two- and three-dimensional hybrid compounds formed by 1,2-, 1,3- and 1,4-cyclohexanedicarboxylates of zinc [J] . Matte H.S.S.R., Swain S.K., Thirumunigan A., Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第12期

机译：由锌的1,2-，1,3-和1,4-环己烷二羧酸盐形成的二维和三维杂化化合物
2. Lamellar and three-dimensional hybrid compounds formed by cyclohexene- and cyclohexanedicarboxylates of Pb, La, and Cd [J] . Rao KP, Thirumurugan A, Rao CNR Chemistry: A European journal . 2007,第11期

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3. Highly diastereoselective Csp~3-Csp~2 Negishi cross-coupling with 1,2-, 1,3- and 1,4-substituted cycloalkylzinc compounds [J] . Tobias Thaler, Benjamin Haag, Andrei Gavryushin Nature Chemistry . 2010,第2期

机译：高度非对映选择性的Csp〜3-Csp〜2 Negishi与1,2-，1,3-和1,4-取代的环烷基锌化合物的交叉偶联
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机译：用N，N'-BIS（3,5-二叔丁基水杨烯）-1,2-二苯基乙烯二氨基氨基聚合，同时对分子量和1,4-C / S选择性的控制在1,3-丁二烯中的聚合中钴与二乙基氯化物组合
5. I. Synthesis of substituted naphthalenes utilizing active nickel. II. Synthesis of substituted naphthoquinones and formation of a charge transfer complex. III. Synthesis of substituted 1,4-diphenyl-2-butenes from (eta(6):eta(6)-1,4-diphenyl-1,3-butadiene)-bis(tricarbonylchromium) [D] . Forkner, Matthew W. 1988

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7. Crown Ethers and Their Alkali Metal Ion Complexes as Assembler Groups in Uranyl–Organic Coordination Polymers with cis-1,3-, cis-1,2-, and trans-1,2-Cyclohexanedicarboxylates [O] . Pierre Thuéry, Youssef Atoini, Jack Harrowfield 2018

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机译：金属 - 金属多重键的反应。 8.通过还原消除（烷基基团歧化）在1,2-mo2R2（Nme2）4化合物（m三键m）与二氧化碳和1,3-日本的反应中形成mo-mo四键

Two- and three-dimensional hybrid compounds formed by 1,2-, 1,3- and 1,4-cyclohexanedicarboxylates of zinc

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