Structural trends in coordination polymers containing perfluorinated dicarboxylates and 4,4'-bipyridine

Hulvey Z.; Ayala E.; Cheetham A.K.

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Structural trends in coordination polymers containing perfluorinated dicarboxylates and 4,4'-bipyridine

机译：含全氟二羧酸盐和4,4'-联吡啶的配位聚合物的结构趋势

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A new family of coordination polymers has been synthesized using cobalt or zinc, 4,4'-bipyridine (4,4'-bpy), and the perfluorinated dicarboxylates tetrafluoroterephthalate (tftpa), tetrafluorophthalate (tfpha), tetrafluoroisophthalate (tfipa), and tetrafluorosuccinate (tfsuc). These materials form under similar conditions and all display similar octahedral metal coordination environments despite significant differences in their structures. The compounds M(4,4'-bpy)(tfipa)-(H_2O)_2 (M= Co, Zn) (1) and M(4,4'-bpy)(tfpha)(H_2O)_2 (M= Co, Zn) (2) are two-dimensional layered structures, whereas Co(4,4'-bpy)-(tfsuc)(H _2O)_2 (3) and M(4,4'-bpy)(tfipa)(H_2O) _2 (M = Co, Zn) (4) display three-dimensional connectivity built up from two types of interconnected chains.

机译：使用钴或锌，4,4'-联吡啶（4,4'-bpy）和全氟二羧酸四氟对苯二甲酸酯（tftpa），四氟邻苯二甲酸酯（tfpha），四氟间苯二甲酸酯（tfipa）和四氟琥珀酸酯合成了新的配位聚合物家族（tfsuc）。这些材料在相似的条件下形成，尽管它们的结构存在显着差异，但它们都显示出相似的八面体金属配位环境。化合物M（4,4'-bpy）（tfipa）-（H_2O）_2（M = Co，Zn）（1）和M（4,4'-bpy）（tfpha）（H_2O）_2（M = Co ，Zn）（2）是二维分层结构，而Co（4,4'-bpy）-（tfsuc）（H _2O）_2（3）和M（4,4'-bpy）（tfipa）（H_2O ）_2（M = Co，Zn）（4）显示由两种类型的互连链建立的三维连通性。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第12期|共5页
作者
Hulvey Z.; Ayala E.; Cheetham A.K.;
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正文语种 eng
中图分类化学;
关键词
4; 4'-bipyridine; Cobalt; Perfluorinated ligands; Polymers; Structure elucidation; Zinc;

机译：4;4'-联吡啶;钴;全氟配体;聚合物;结构解析;锌;

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1. Structural trends in coordination polymers containing perfluorinated dicarboxylates and 4,4'-bipyridine [J] . Hulvey Z., Ayala E., Cheetham A.K. Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第12期

机译：含全氟二羧酸盐和4,4'-联吡啶的配位聚合物的结构趋势
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机译：三种过渡金属4,4'-联吡啶配位聚合物的结构，热和磁性能：[Ni（4,4'-联吡啶）（3）（H2O）（2）]（ClO4）（2）中心点1.4 （4,4'-bipy）中心点3（H2O）; [Co（4,4'-bipy）（3）（H2O）（2）]（ClO4）（2）中心点1.4（4,4'-b
3. Acid directed in situ oxidation and decarboxylation of 4,4′,6, 6′-tetra-methyl-2,2′-bipyridine: Synthesis and structural characterisation of 4,4′,6-tri-carboxy-2,2′-bipyridine and its copper(II) coordination polymer [J] . Kelly N.R., Goetz S., Hawes C.S., Inorganica Chimica Acta . 2013,第Null期

机译：酸对4,4'，6,6'-四甲基-2,2'-联吡啶进行原位氧化和脱羧：4,4'，6-三羧基-2,2'-的合成和结构表征联吡啶及其铜（II）配位聚合物
4. Synthesis and Photophysical Properties of Silver(I) Coordination Polymers with 4,4'-Bipiperidine and 4,4'-Bipyridine [C] . Tsubasa Yoshioka, Satoshi Sugimoto, Sota Takeuchi 日本化学会春季年会講演予稿集 . 2018

机译：用4,4'-双哌啶和4,4'-硼吡啶的银（I）配位聚合物的合成和光药性能
5. Synthesis of metal-organic frameworks containing perfluorinated dicarboxylates [D] . Hulvey, Zeric 2010

机译：含全氟二羧酸盐的金属有机骨架的合成
6. Crystal Structures Hirshfeld Surfaces and Thermal Study of Isostructural Polymeric Ladders of La(III) and Sm(III) Coordination Compounds with 44’-Bipyridine and Dibromoacetates [O] . Agnieszka Czylkowska, Anna Pietrzak, Małgorzata Szczesio, 2020

机译：La（III）和SM（III）和SM（III）配位化合物的晶体结构HIRSHFELD表面和热学研究具有44-吡啶和二溴乙酸酯
7. Structural trends in coordination polymers containing perfluorinated dicarboxylates and 4,4'-bipyridine [O] . Hulvey, Zeric, Ayala, Elizabeth, Cheetham, Anthony K. 2009

机译：含全氟二羧酸盐和4,4'-联吡啶的配位聚合物的结构趋势

Structural trends in coordination polymers containing perfluorinated dicarboxylates and 4,4'-bipyridine

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