Synthesis and Characterization of beta-Diketiminate Zinc Complexes

Schulz S; Eisenmann T; Westphal U; Schmidt S; Florke U

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Synthesis and Characterization of beta-Diketiminate Zinc Complexes

机译：β-二甲叉基锌配合物的合成与表征

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The monomeric beta-diketiminate zinc complex (Mes)NacNacZnMe 1 (MesNacNac = {[2,6-(2,4,6-Me-3-C6H2)N(Me)C)](2)CH}) was obtained in almost quantitative yield from the reaction of ZnMe2 with (Mes)NacNacH. Reaction of 1 with either Me3NHCl or a Solution of HCl in Et2O yielded (Mes)NacNacZnCl 2, whereas (Mes)NacNacZnI 3 was obtained from the reaction of I with I-2. 1-3 were characterized by elemental analyses, mass and multinuclear (1H, C-13{H-1}) NMR spectroscopy, 3 center dot THF also by single crystal X-ray analysis.

机译：在以下条件下获得了单体β-二酮化锌络合物（Mes）NacNacZnMe 1（MesNacNac = {[2,6-（2,4,6-Me-3-C6H2）N（Me）C）]（2）CH} ZnMe2与（Mes）NacNacH的反应几乎可以定量收率。 1与Me3NHCl或HCl在Et2O中的溶液反应生成（Mes）NacNacZnCl 2，而（Mes）NacNacZnI 3从I与I-2的反应获得。通过元素分析，质量和多核（1H，C-13 {H-1}）NMR谱，1-3中心点THF也通过单晶X射线分析来表征1-3。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第2期|共5页
作者
Schulz S; Eisenmann T; Westphal U; Schmidt S; Florke U;
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正文语种 eng
中图分类化学;
关键词
Zinc; beta-Diketiminate; Crystal structures; DFT calculation; RING-OPENING POLYMERIZATION; SINGLE-SITE CATALYSTS; ALTERNATING COPOLYMERIZATION; STRUCTURAL-CHARACTERIZATION; METAL-COMPLEXES; CARBON-DIOXIDE; CYCLOHEXENE OXIDE; CYCLIC ESTERS; DERIVATIVES; CHEMISTRY;

机译：锌;β-二酮亚胺;晶体结构;DFT计算;开环聚合;单部位催化剂;交替共聚;结构表征;金属络合物;碳二氧化物;环己氧化物;环氧化物;环氧化物;

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Synthesis and Characterization of beta-Diketiminate Zinc Complexes

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