An Old Reaction with New Results: The Unexpected Formation of a Rare Earth Metal Cluster Containing Six Europium Atoms

Tauscher E; Beckert R; Weiss D; Gorls H; Birckner E

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An Old Reaction with New Results: The Unexpected Formation of a Rare Earth Metal Cluster Containing Six Europium Atoms

机译：具有新结果的旧反应：包含六个Formation原子的稀土金属簇的意外形成

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Employing a standard protocol for the preparation of a trisbenzoylacetonato europium(III) complex with 4-bromo, benzoylacetone 2 as ligand, a new europium species was synthesized and characterized. The X-ray crystal structure analysis revealed a new europium cluster consisting of six europium-centres.

机译：采用标准方案制备以4-溴苯甲酰丙酮2为配体的三苯甲酰丙酮基euro（III）配合物，合成并表征了一种新的euro。 X射线晶体结构分析显示了一个新的由六个euro中心组成的cluster簇。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第1期|共3页
作者
Tauscher E; Beckert R; Weiss D; Gorls H; Birckner E;
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正文语种 eng
中图分类化学;
关键词
Lanthanides; Carbonyl complexes; Cluster compounds; Fluorescence; Crystal structure;

机译：镧系;羰基配合物;簇合物;荧光;晶体结构;

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1. An Old Reaction with New Results: The Unexpected Formation of a Rare Earth Metal Cluster Containing Six Europium Atoms [J] . Tauscher E, Beckert R, Weiss D, Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第1期

机译：具有新结果的旧反应：包含六个Formation原子的稀土金属簇的意外形成
2. Ab initio properties of the ground-state polar and paramagnetic europium-alkali-metal-atom and europium-alkaline-earth-metal-atom molecules [J] . Micha? Tomza Physical Review, A. Atomic, molecular, and optical physics . 2014,第2aPta1期

机译：基态极性和顺磁性euro-碱金属原子和euro-碱土金属原子分子的从头算性质
3. Methylidene rare-earth-metal complex mediated transformations of C=N, N=N and N-H Bonds: New routes to imido rare-earth-metal clusters [J] . Hong J., Zhang L., Wang K., Chemistry: A European journal . 2013,第24期

机译：亚甲基稀土金属络合物介导的C = N，N = N和N-H键的转变：亚氨基稀土金属簇的新途径
4. Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well Defined Polyoxo Rare Earth Metal Clusters [C] . Takanori Shima, Zhaomin Hou Symposium on Organometallic Chemistry . 2006

机译：四核稀土金属聚醇配合物氢化一氧化碳。乙烯选择性形成和良好定义的Polyoxo稀土金属簇分离
5. Photoemission study of the rare earth intermetallic compounds: (R)nickel-germanium (R) = europium, gadolinium. [D] . Park, Jongik. 2004

机译：稀土金属间化合物的光发射研究：（R）镍锗（R）= ,、 g。
6. The importance of the counter-cation in reductive rare-earth metal chemistry: 18-crown-6 instead of 222-cryptand allows isolation of YII(NR2)31− and ynediolate and enediolate complexes from CO reactions [O] . Austin J. Ryan, Joseph W. Ziller, William J. Evans 2020

机译：反阳离子在还原性稀土金属化学中的重要性：18冠-6而不是222-碱基允许分离yii（nr2）3 1-和ynediolate和来自CO反应的对己二酸酯复合物
7. Ab initio properties of the ground-state polar and paramagnetic europium-alkali-metal-atom and europium-alkaline-earth-metal-atom molecules [O] . Tomza, Michał 2014

机译：基态极性和顺磁性的从头算特性铕 - 碱金属 - 原子和铕 - 碱土金属 - 原子分子
8. The Dicarbides of Europium and Other Rare-Earth Metals [R] . N. N. Matiushenko, O. P. Svinarenko 1969

机译：铕和其他稀土金属的Dicarbides

An Old Reaction with New Results: The Unexpected Formation of a Rare Earth Metal Cluster Containing Six Europium Atoms

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