Structural Variety in the Pseudo-ternary System M/Ge/I: alpha-[NMe(nBu)(3)](GeI4)I, beta-[NMe(nBu)(3)](GeI4)I and [ImMe(nBu)][N(nBu)(4)](GeI4)(3)I-2

Wolff M; Feldmann C

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Structural Variety in the Pseudo-ternary System M/Ge/I: alpha-[NMe(nBu)(3)](GeI4)I, beta-[NMe(nBu)(3)](GeI4)I and [ImMe(nBu)][N(nBu)(4)](GeI4)(3)I-2

机译：伪三元系统M / Ge / I中的结构多样性：alpha- [NMe（nBu）（3）]（GeI4）I，β-[NMe（nBu）（3）]（GeI4）I和[ImMe（nBu））] [N（nBu）（4）]（GeI4）（3）I-2

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By reaction of GeI4, [N(nBU)(4)]1 as iodide donor, and [NMe(nBu)(3)][N(Tf)(2)] as ionic liquid, reddish-black, plate-like shaped crystals are obtained. X-ray diffraction analysis of' single crystals resulted in the compositions alpha-[NMe(nBu)(3)](GeI4)I (Pbca; a = 1495.4(3) pm; b = 1940.6(4) pm; c = 3643.2(7) pm; Z = 16) and beta-[NMe(nBu)(3)](GeI4)I (Pn; a = 1141.5(2) pm; b = 953.6(2) pm; c = 1208.9(2) pm; beta = 100.8(1)degrees; Z = 2). Depending on the reaction temperature, the one or other compound is formed selectively In addition, the reaction of GeI4 and [N(nBu)(4)]I, using [ImMe(nBu)][BF4] (Im = imidazole) as ionic liquid, resulted in the crystallization of [ImMe(nBu)][N(nBu)(4)](GeI4)(3)I-2 (P2(1)/c; a = 1641.2(3) pm; b = 1903.0(4) pm; c = 1867.7(4) pm, beta = 92.0(1)degrees; Z = 4). The anionic network of all three compounds is established by molecular gemanium(IV)iodide, which is bridged by iodide anions. The different connectivity of (GeI4-I-) networks is attributed to the flexibility of I- regarding its coordination and bond length. Here, a [3+1]-, 4- and 5-fold coordination is first observed in the pseudo-ternary system M/Ge/I (M: cation).

机译：通过GeI4，作为碘化物供体的[N（nBU）（4）] 1和作为离子液体的[NMe（nBu）（3）] [N（Tf）（2）]的反应，红黑色，板状获得晶体。单晶的X射线衍射分析得出成分为α-[NMe（nBu）（3）]（GeI4）I（Pbca; a = 1495.4（3）pm; b = 1940.6（4）pm; c = 3643.2 （7）pm; Z = 16）和beta- [NMe（nBu）（3）]（GeI4）I（Pn; a = 1141.5（2）pm; b = 953.6（2）pm; c = 1208.9（2） pm;β= 100.8（1）度; Z = 2）。根据反应温度，选择性地形成一种或另一种化合物。另外，使用[ImMe（nBu）] [BF4]（Im =咪唑）作为离子型，GeI4与[N（nBu）（4）] I的反应液体，导致[ImMe（nBu）] [N（nBu）（4）]（GeI4）（3）I-2（P2（1）/ c; a = 1641.2（3）pm; b = 1903.0 （4）pm; c = 1867.7（4）pm，beta = 92.0（1）度; Z = 4）。这三种化合物的阴离子网络都是由分子碘化锗（IV）建立的，分子碘化碘桥接。（GeI4-I-）网络的不同连接性归因于I-在其协调性和绑定长度方面的灵活性。在此，首先在伪三元系统M / Ge / I（M：阳离子）中观察到[3 + 1]-，4和5倍的配位。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第8期|共8页
作者
Wolff M; Feldmann C;
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正文语种 eng
中图分类化学;
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Germanium; Iodine; Ionic liquids; Coordination modes; Structure elucidation;

机译：锗;碘;离子液体;配位模式;结构阐明;

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1. Structural Variety in the Pseudo-ternary System M/Ge/I: alpha-[NMe(nBu)(3)](GeI4)I, beta-[NMe(nBu)(3)](GeI4)I and [ImMe(nBu)][N(nBu)(4)](GeI4)(3)I-2 [J] . Wolff M, Feldmann C Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第8期

机译：伪三元系统M / Ge / I中的结构多样性：alpha- [NMe（nBu）（3）]（GeI4）I，β-[NMe（nBu）（3）]（GeI4）I和[ImMe（nBu））] [N（nBu）（4）]（GeI4）（3）I-2
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机译：铜（I）配位聚合物[{Cu（mu-X）}（2）{RP（mu-（NBu）-Bu-t）}（2）]（n）（R = OC6H4OMe-o; X = Cl， Br和I）及其可逆转化为单核络合物[CuX {（RP（mu-（NBu）-Bu-t））（2）}（2）：合成和结构表征
3. Ring systems incorporating the ambidentate dianions [(BuN)-Bu-t(E)P(mu-(NBu)-Bu-t)(2)P(E)(NBu)-Bu-t](2-)(E = S, Se) [J] . Chivers T., Parvez M., Schatte G., Phosphorus, Sulfur, and Silicon and the Related Elements . 2001,第0期

机译：ring systems incorporating the啊M币dentate点ions [(bun)-B U-他(E)P(木-(NB U)-B U-他)(2)P(E)(NB U)-B U-他](2-)(E = S, S俄)
4. Stability Conditions of a Multiclass System with NBU Retrials [C] . Evsey Morozov, Ruslana Nekrasova International Conference on Queueing Theory and Network Applications . 2019

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5. Pd@nBu4Br as a Simple Catalytic System for N-Alkylation Reactions with Alcohols [O] . Bastien Cacciuttolo, Oana Pascu, Cyril Aymonier, 2016

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Structural Variety in the Pseudo-ternary System M/Ge/I: alpha-[NMe(nBu)(3)](GeI4)I, beta-[NMe(nBu)(3)](GeI4)I and [ImMe(nBu)][N(nBu)(4)](GeI4)(3)I-2

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