Cadmium(II) complexes with a bulky anthracene-based carboxylate ligand: Syntheses, crystal structures, and luminescent properties

Liu C.-S.; Wang J.-J.; Chang Z.; Yan L.-F.

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Cadmium(II) complexes with a bulky anthracene-based carboxylate ligand: Syntheses, crystal structures, and luminescent properties

机译：具有大量蒽基羧酸盐配体的镉（II）配合物：合成，晶体结构和发光性质

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摘要

To explore the coordination possibilities of anthracenebased ligands, three cadmium(II) complexes with anthracene-9-carboxylate (L) and relevant auxiliary chelating or bridging ligands were synthesized and characterized: Cd _2(L)_4(2bpy)_2(μ-H_2O (1), Cd _2(L)_4(phen)_2(μ-H_2O) (2), and {[Cd_3(L)_6(4bPy)]}~∞ (3) (2bpy = 2, 2'bipyridine, phen = 1, 10-phenanthroline, and 4bpy = 4, 4'-bipyridine). Structural analyses show that complexes 1 and 2 both take dinuclear structures by incorporating the chelating 2bpy or phen ligand, which are further interlinked by intermolecular hydrogen-bonding, TI-JI stacking, and/or C-H?π supramolecular interactions to generate higher-dimensional supramolecular frameworks. Complex 3 has a onedimensional (ID) ribbon-like structure, which is further assembled into a two-dimensional (2D) layer, and a three-dimensional (3D) framework by the co-effects of interchain C-H?O hydrogen-bonding and C-H?π supramolecular interactions. Moreover, the luminescent properties of these complexes were further investigated in detail.

机译：为了探索蒽基配体的配位可能性，合成了三种与蒽-9-羧酸盐（L）和相关辅助螯合或桥连配体的镉（II）配合物，并进行了表征：Cd _2（L）_4（2bpy）_2（μ-H_2O）（1），Cd _2（L）_4（phen）_2（μ-H_2O）（2）和{[Cd_3（L）_6（4bPy）]}〜∞（3）（2bpy = 2，2'bipyridine， phen = 1、10-菲咯啉和4bpy = 4、4'-联吡啶）。结构分析表明，配合物1和2均通过掺入螯合的2bpy或phen配体而具有双核结构，并通过分子间氢键进一步相互连接， TI-JI堆叠和/或CH？π超分子相互作用生成更高维的超分子骨架配合物3具有一维（ID）带状结构，该结构进一步组装成二维（2D）层，链间CH 2 O氢键和CH 2π超分子相互作用的共同作用形成三维（3D）框架。这些复合物的进一步详细研究。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2010年第6期|共9页
作者
Liu C.-S.; Wang J.-J.; Chang Z.; Yan L.-F.;
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正文语种 eng
中图分类化学;
关键词
Anthracene; Bipyridine; Cadmium; Luminescence; X-ray diffraction;

机译：蒽;联吡啶;镉;发光;X射线衍射;

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专利

1. Cadmium(II) complexes with a bulky anthracene-based carboxylate ligand: Syntheses, crystal structures, and luminescent properties [J] . Liu C.-S., Wang J.-J., Chang Z., Zeitschrift fur Anorganische und Allgemeine Chemie . 2010,第6期

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2. Silver(I) Complexes with a Bulky Anthracene-Based Dicarboxylic Ligand: Syntheses, Crystal Structures, and Luminescent Properties [J] . Liu Chun-Sen, Wang Jun-Jie, Chang Ze, Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第3期

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Cadmium(II) complexes with a bulky anthracene-based carboxylate ligand: Syntheses, crystal structures, and luminescent properties

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