Infinite coordination polymers of one- and two-dimensional cobalt acetates

Zhang G.; Lin J.; Guo D.-W.; Yao S.-Y.; Tian Y.-Q.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Infinite coordination polymers of one- and two-dimensional cobalt acetates

【24h】

Infinite coordination polymers of one- and two-dimensional cobalt acetates

机译：一维和二维乙酸钴的无限配位聚合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Two coordination polymers of cobalt acetate, [Co_5(O _2CMe)_(10)] (1) and [Co(O_2CMe)_2(H _2O)]·H_2O (2), were solvothermally synthesized and characterized by single-crystal and powder Xray diffraction analyses, IR spectroscopy, and elemental analysis. Compound 1 crystallizes in orthorhombic space group Pbcn in two-dimensional layers, which consist of 12-membered cobalt rings. Compound 2 crystallizes in monoclinic space group C2/m and exhibits one-dimensional chains, which are bridged by one water molecule and two acetate ligands in (2.11)- and. (2.20)-modes. Preliminary magnetic studies revealed that antiferromagnetic couplings exist in both compounds.

机译：溶剂热合成了乙酸钴的两种配位聚合物[Co_5（O _2CMe）_（10）]（1）和[Co（O_2CMe）_2（H _2O）]·H_2O（2），并用单晶和粉末表征。 X射线衍射分析，红外光谱和元素分析。化合物1在由12元钴环组成的二维正交晶空间群Pbcn中结晶。化合物2在单斜空间群C2 / m中结晶并显示一维链，该链由（2.11）-和中的一个水分子和两个乙酸酯配体桥接。（2.20）模式。初步的磁性研究表明，两种化合物中都存在反铁磁耦合。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2010年第7期|共4页
作者
Zhang G.; Lin J.; Guo D.-W.; Yao S.-Y.; Tian Y.-Q.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Cobalt; Magnetic properties; Polymers; Solvothermal synthesis; X-ray diffraction;

机译：钴;磁性;聚合物;溶剂热合成;X射线衍射;

相似文献

外文文献
中文文献
专利

1. Infinite coordination polymers of one- and two-dimensional cobalt acetates [J] . Zhang G., Lin J., Guo D.-W., Zeitschrift fur Anorganische und Allgemeine Chemie . 2010,第7期

机译：一维和二维乙酸钴的无限配位聚合物
2. Self-Assembly of Right-Handed Helical Infinite Chain,One- and Two-Dimensional Coordination Polymers Tuned via Anions [J] . Long Yi, Xing Yang, Tongbu Lu Crystal growth & design . 2005,第3期

机译：通过阴离子调节的右旋螺旋无限链，一维和二维配位聚合物的自组装
3. One- and two-dimensional CdII coordination polymers constructed from 2-(2-methyl-1H-benzimidazol-1-yl)acetate ligands [J] . Qiang Li, Hui-Ting Wang Qiong Ye Acta crystallographica. Section C, Structural chemistry. . 2014,第10期

机译：由2-（2-甲基-1H-苯并咪唑-1-基）乙酸酯配体构成的一维和二维CdII配位聚合物
4. Key Role of Metal-Coordination in Cobalt- Mediated Radical Polymerization of Vinyl Acetate [C] . Symposium on controlled/living radical polymerization . 2009

机译：金属配位在乙酸乙烯酯的钴介导的自由基聚合中的关键作用
5. Synthesis and applications of one- and two-dimensional polymer-carbon nanomaterial composites. [D] . Seo, Wanji. 2016

机译：一维和二维聚合物-碳纳米材料复合材料的合成与应用。
6. Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures [O] . David K. Geiger, Dylan E. Parsons, Bracco A. Pagano 2016

机译：两种具有桥联乙酸盐和苯二二胺配体的镉配位聚合物具有二维层状结构
7. Self-Assembly of One- and Two-Dimensional Coordination Polymers with Quinonoid Backbones Featuring Coinage Metals as Nodes [O] . -1

机译：用醌骨骨架的单维和二维协调聚合物的自组装具有鸡核金属作为节点。
8. Inorganic Coordination Polymers. VIII. Cobalt(II) and Zinc(II) Phosphinate Polymers and Copolymers. [R] . Rose, S. H., Block, B. P. 1965

机译：无机配位聚合物。八。钴（II）和锌（II）次膦酸盐聚合物和共聚物。

Infinite coordination polymers of one- and two-dimensional cobalt acetates

摘要

著录项

相似文献

相关主题

期刊订阅