Tri- and tetracoordinate copper(I) complexes of 1,1′- diisocyanoferrocene

Siemeling U.; Klapp L.R.R.; Bruhn C.

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Tri- and tetracoordinate copper(I) complexes of 1,1′- diisocyanoferrocene

机译：1,1'-二异氰基二茂铁的三配位和四配位铜（I）配合物

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Two homoleptic copper(I) complexes of the bidentate isocyanide 1,1~′-diisocyanoferrocene (1) were prepared and structurally characterised. The dications present in [Cu_2(μ-1)_3] [PF _6]_2 exhibit a paddlewheel-like structure with trigonal-planar Cu~I. These dications are connected in a chain-like fashion by bridging ligands 1 in the coordination polymer [{Cu _2(μ-l)_3}(μ-1)]_n(OTf)_(2n), which contains tetracoordinate CuI in a distorted tetrahedral coordination environment. The hexafluorophosphate analogue of the latter compound was also prepared.

机译：制备了二齿异氰化物1,1〜'-二异氰基二茂铁（1）的两种均化铜（I）配合物，并对其结构进行了表征。 [Cu_2（μ-1）_3] [PF _6] _2中存在的标记显示出具有三角平面Cu〜I的桨轮状结构。这些指示通过桥接配位聚合物[{Cu _2（μ-l）_3}（μ-1）] _ n（OTf）_（2n）中的配位体1桥连成链状连接。扭曲的四面体协调环境。还制备了后一种化合物的六氟磷酸酯类似物。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2010年第4期|共4页
作者
Siemeling U.; Klapp L.R.R.; Bruhn C.;
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正文语种 eng
中图分类化学;
关键词
Copper; Crystal structures; Ferrocene; Iron; Isocyanide ligands;

机译：铜;晶体结构;二茂铁;铁;异氰酸酯配体;

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1. Tri- and tetracoordinate copper(I) complexes of 1,1′- diisocyanoferrocene [J] . Siemeling U., Klapp L.R.R., Bruhn C. Zeitschrift fur Anorganische und Allgemeine Chemie . 2010,第3a4期

机译：1,1'-二异氰基二茂铁的三配位和四配位铜（I）配合物
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Tri- and tetracoordinate copper(I) complexes of 1,1′- diisocyanoferrocene

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