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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Reactions of Aluminium(I) iodide [German]
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Reactions of Aluminium(I) iodide [German]

机译:碘化铝(I)的反应[德语]

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摘要

By co-condensation of a mixture of solvents (toluene and a donor species (Do)) together with the high-temperature molecule ALT. metastable solutions are obtained which are suitable starting materials for different reactions: the reaction with sulfur leads to Do(I)Al-(mu(2)-S)(2)-Al(I)Do; together with dimeric Cp*MgCl . OEt2 an unexpected redox reaction ends up with (eta(1)-Cp*)AlI2 . OEt2; treatment with DME results in an intermediate of ether-cleavage: (Me(I)AlOC2H4OMe)(2). These three compounds have been structurally analyzed by means of X-ray methods. - NMR-spectroscopic techniques provide evidence of Al-I-species stabilized by interaction with aromatic compounds. This conclusion could be confirmed with the help of ab initio calculations. [References: 30]
机译:通过溶剂(甲苯和供体物质(Do))的混合物与高温分子ALT的共缩合。获得亚稳溶液,其是用于不同反应的合适的起始原料:与硫的反应导致Do(I)Al-(mu(2)-S)(2)-Al(I)Do;与二聚体Cp * MgCl一起。 OEt2一个意外的氧化还原反应最终以(eta(1)-Cp *)AlI2结束。 OEt2;用DME处理会产生醚裂解中间体:(Me(I)AlOC2H4OMe)(2)。这三种化合物已经通过X射线方法进行了结构分析。 -NMR光谱技术提供了通过与芳族化合物相互作用而稳定化的Al-I物种的证据。该结论可以通过从头算计算得到证实。 [参考:30]

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