Anion effects on the formation of silver(I) complexes with the flexible ligand 4,4′-Bis(1,2,4-triazol-1-ylmethyl)biphenyl

Ni T.; Zhao Y.; Shao M.; Zhu S.; Xing F.; Li M.

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Anion effects on the formation of silver(I) complexes with the flexible ligand 4,4′-Bis(1,2,4-triazol-1-ylmethyl)biphenyl

机译：阴离子对柔性配体4,4'-双（1,2,4-三唑-1-基甲基）联苯的银（I）配合物形成的影响

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The reaction of 4,4′-bis(1,2,4-triazol-1-ylmethyl)biphenyl (btmb) with silver(I) salts of BF4-, NO3- and N3- led to the formation of four new silver(I) coordination polymers {[Ag(btmb)]BF4}n (1), {[Ag 2(btmb)3](NO3)2(H2O) 5}n (2), [Ag2(btmb)(N3) 2]n (3), and [Ag(btmb)(N3)]n (4). Their coordination number varies from 2 (in 1) to 3 (in 2), 4 (in 3), and 5 (in 4). Different from the single chain structure of 1, complex 2 displays a 1D ladder-like double chain framework, whereas complex 3 exhibits a 2D layered architecture. Complex 4 has the same anion as complex 3 but shows a different metal-to-ligand ratio and a 1D double-zigzag chain structure. Both 3 and 4 have Ag?Ag argentophilic interactions. The ligand btmb adopts both cis or trans configuration in the studied complexes. A trans- or cis-btmb ligand link silver ions with Ag?Ag distances of ≈18 and 13 ?, respectively. BF4- and NO3- are non-coordinating anions in 1 and 2. N3- is the bridging anion in 3 (1,3-bridging fashion) and 4 (1,1-bridging fashion). These findings suggest that the coordination numbers around the AgI ion correlate to the coordination abilities of anions and the btmb to silver ratio. In addition, the influence of anions on thermal stability were also investigated. This work is a good example that nicely supports the less explored field of anion-dependent structures of complexes with non-pyridyl ligands.

机译：4,4'-双（1,2,4-三唑-1-基甲基）联苯（btmb）与BF4-，NO3-和N3-的银（I）盐的反应导致形成四个新的I）配位聚合物{[Ag（btmb）] BF4} n（1），{[Ag 2（btmb）3]（NO3）2（H2O）5} n（2），[Ag2（btmb）（N3）2 ] n（3）和[Ag（btmb）（N3）] n（4）。它们的协调数从2（合1）到3（合2），4（合3）和5（合4）不等。与1的单链结构不同，复合物2显示1D梯形双链框架，而复合物3显示2D分层结构。配合物4具有与配合物3相同的阴离子，但是显示出不同的金属与配体比率和一维双Z字形链结构。 3和4都具有Ag？Ag亲银性相互作用。在所研究的复合物中，配体btmb采用顺式或反式构型。反式或顺式-btmb配体连接银离子的Ag？Ag距离分别约为≈18和13?。 BF4-和NO3-是1和2中的非配位阴离子。N3-是3（1,3-桥接）和4（1,1-桥接）的桥连阴离子。这些发现表明，AgI离子周围的配位数与阴离子的配位能力以及btmb与银的比例有关。此外，还研究了阴离子对热稳定性的影响。这项工作是一个很好的例子，很好地支持了非吡啶基配体配合物的阴离子依赖性结构的较少探索领域。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2011年第6期|共9页
作者
Ni T.; Zhao Y.; Shao M.; Zhu S.; Xing F.; Li M.;
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正文语种 eng
中图分类化学;
关键词
4; 4′-Bis(1; 2; 4-triazole-1-ylmethyl)biphenyl; Anion effect; Crystal structure; Metal-organic frameworks; Silver;

机译：4;4'-Bis（1;2;4-三唑-1-基甲基）联苯;阴离子效应;晶体结构;金属有机骨架;银;

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1. Anion effects on the formation of silver(I) complexes with the flexible ligand 4,4′-Bis(1,2,4-triazol-1-ylmethyl)biphenyl [J] . Ni T., Zhao Y., Shao M., Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第6期

机译：阴离子对柔性配体4,4'-双（1,2,4-三唑-1-基甲基）联苯的银（I）配合物形成的影响
2. Synthesis, spectral, thermal, XRD and theoretical investigation of dimeric complexes with bis-bidentate ON-NO donor azodye ligand, 4,4 '-(1E,1 ' E)-biphenyl-4,4 '-diylbis(diazene-1,1-diyl)bis(4-nitrophenol) [J] . Mahapatra Bipin Bihari, Sarangi Ashish Kumar, Mishra Ramani Ranjan Journal of the Indian Chemical Society . 2016,第1期

机译：具有双双齿ON-NO供体偶氮染料配体4,4'-（1E，1'E）-联苯-4,4'-二基双（二氮杂-1）的二聚体配合物的合成，光谱，热，XRD和理论研究1-二基）双（4-硝基苯酚）
3. Anion-assisted silver(I) coordination complexes from flexible unsymmetrical bis(pyridyl) ligands: Syntheses, structures and luminescent properties [J] . Zhang Z.-Y., Deng Z.-P., Huo L.-H., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第Null期

机译：柔性不对称双（吡啶基）配体的阴离子辅助银（I）配合物：合成，结构和发光性质
4. Spectroelectrochemical Study of the Formation of Radical Cations of 4,4'-bisN-(l- naphthyl)-N-phenyl-amino-biphenyl as a Hole Transport Semiconductor Material [C] . Sharavsambuu Baasanjav, Gendensvren Bolormaa, Batjargal Naranbileg, MRS fall meeting . 2012

机译：用作空穴传输半导体材料的4,4'-双N-（1-萘基）-N-苯基-氨基-联苯的自由基阳离子形成的光谱电化学研究
5. Synthesis and luminescence of organometallic complexes. Part I: Rhenium(I) carbonyl complexes and their ligands in anion recognition. Part II: Chiral ferrocenyl-substituted N-heterocyclic carbene ligands [D] . Odago, Maurice Otieno 2010

机译：有机金属配合物的合成和发光。第一部分：R（I）羰基配合物及其配体在阴离子识别中的作用。第二部分：手性二茂铁基取代的N-杂环卡宾配体
6. catena-Poly[[[aquasilver(I)]-μ-1,1′-(butane-1,4-diyl)di-1H-imidazole-κ2N3:N3′] hemi(biphenyl-4,4′-dicarboxylate) dihydrate] [O] . Zheyu Zhang 2016

机译：阳离子-聚[[[[aquasilver（I）]]-μ-1,1'-（butane-1,4-diyl）di-1H-imidazole-κ2ñ3：N3']半（联苯-4,4'-二羧基酸酯）二水合物]
7. Silver Coodination Polymers with Flexible Ligands. Syntheses, Crystal Structures, and Effect of the Counteranion and the Solvent on the Structure of Complexes AgL1X of the Bis(Phenylthio)methane Ligand L1 with Silver(I) Salts, X = ClO4-, BF4-, CF3COO-, CF3SO3-, CF3CF2CF2COO-, and -OOCCF2CF2COO- [O] . -1

机译：含有柔性配体的银色瓦瓦丁聚合物。合成，晶体结构和对抗的效果和溶剂对双（苯硫基）甲烷配体L1与银（I）盐的络合物Ag11x结构，X = ClO4-，BF4-，CF3COO-，CF3SO3- ，cf3cf2cf2coo-，和-ooccf2cf2coo-

Anion effects on the formation of silver(I) complexes with the flexible ligand 4,4′-Bis(1,2,4-triazol-1-ylmethyl)biphenyl

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