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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >A 1D → 3D two-fold interpenetration array formed by hydrogen-bonding interactions
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A 1D → 3D two-fold interpenetration array formed by hydrogen-bonding interactions

机译:通过氢键相互作用形成的1D→3D双重互穿阵列

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摘要

The self-assembly of 4'-hydroxy-biphenyl-4-carboxylic acid (H _2hbc), 4, 4'-bipyridine (4, 4'-bpy) with a cobalt salt under hydrothermal conditions yielded a novel dinuclear cobalt(II) coordination polymer, {[Co(Hhbc) _2(4, 4'-bpy)]·H _2O} _n (1), where the coordinating polymeric chains are connected together through hydrogen bonding into a 3D framework of the primitive cubic (pcu) topology. Two pcu frameworks are interweaved into a 3D twofold Class Ia interpenetrating array.
机译:在水热条件下4'-羟基-联苯-4-羧酸(H _2hbc),4,4'-联吡啶(4,4'-bpy)与钴盐的自组装产生了新型双核钴(II)配位聚合物{[Co(Hhbc)_2(4,4'-bpy)]·H _2O} _n(1),其中配位聚合物链通过氢键连接到原始立方(pcu)的3D框架中拓扑。将两个pcu框架交织为3D双重Ia类互穿数组。

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