Three new lanthanide coordination polymers built from H 2bpdc ligands: Syntheses, structures, and properties

Sun Y.-G.; Lv T.-Y.; Gao X.; Xiong G.; Sun D.; He L.-L.; Xu Z.-H.; Wang S.-J.; Ding F.

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Three new lanthanide coordination polymers built from H 2bpdc ligands: Syntheses, structures, and properties

机译：由H 2bpdc配体构建的三种新型镧系配位聚合物：合成，结构和性质

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Three new lanthanide-organic coordination polymers, {[Ln _2(bpdc) _2(H _2O) _6(NO _3)]·NO _3} [Ln = La (1), Ce (2), Pr (3)] (H _2bpdc = 2, 2'-bipyridine-6, 6'-dicarboxylic acid) were synthesized under hydrothermal conditions and structurally characterized by elemental analysis, IR spectroscopy as well as single-crystal and powder X-ray diffraction. Single-crystal X-ray diffraction analysis revealed that compounds 1-3 are isostructural, composed of two dimensional honeycomb network linked by bpdc ligands. The magnetic property of compound 3 was investigated

机译：三种新的镧系-有机配位聚合物，{[Ln _2（bpdc）_2（H _2O）_6（NO _3）]·NO _3} [Ln = La（1），Ce（2），Pr（3）] [H在水热条件下合成了_2bpdc = 2、2'-联吡啶-6、6'-二羧酸），并通过元素分析，红外光谱以及单晶和粉末X射线衍射对其结构进行了表征。 X射线单晶衍射分析表明，化合物1-3是同构的，由bpdc配体连接的二维蜂窝网络组成。研究化合物3的磁性

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第14期|共5页
作者
Sun Y.-G.; Lv T.-Y.; Gao X.; Xiong G.; Sun D.; He L.-L.; Xu Z.-H.; Wang S.-J.; Ding F.;
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正文语种 eng
中图分类化学;
关键词
Coordination polymers; Crystal structure; Lanthanides; Magnetic properties;

机译：配位聚合物;晶体结构;镧系元素;磁性;

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1. Three new lanthanide coordination polymers built from H 2bpdc ligands: Syntheses, structures, and properties [J] . Sun Y.-G., Lv T.-Y., Gao X., Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第14期

机译：由H 2bpdc配体构建的三种新型镧系配位聚合物：合成，结构和性质
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Three new lanthanide coordination polymers built from H 2bpdc ligands: Syntheses, structures, and properties

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