Electronic structures of highly symmetrical compounds of f elements. 45 ~([1]) unusual spectrochemical properties of the triphenylphosphinoxido ligand in the case of mono and bis adducts of homoleptic samarium(III) silylamides

Jank S.; Reddmann H.; Zhang L.; Amberger H.-D.

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Electronic structures of highly symmetrical compounds of f elements. 45 ~([1]) unusual spectrochemical properties of the triphenylphosphinoxido ligand in the case of mono and bis adducts of homoleptic samarium(III) silylamides

机译：f元素高度对称的化合物的电子结构。在均化sa（III）甲硅烷基酰胺的单加合物和双加合物的情况下，三苯基膦氧化配体具有45〜（[1]）的异常光谱化学性质

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The optical spectra of the mono tetrahydrofuran (1), mono triphenylphosphinoxide (2) and bis cyclohexylisocyanide (3) adducts of the tris(bis(trimethylsilyl)amido)samarium(III) (Sm(btmsa) _3) moiety as well as those of the bis tetrahydrofuran (4) and partly those of the bis triphenylphosphinoxide (5) of the tris(bis(dimethylsilyl)amido)samarium(III) moiety have been recorded at room and low temperatures. From the spectra obtained, the underlying crystal field splitting patterns could be derived, and simulated by fitting the free parameters of a phenomenological Hamiltonian. The values of the crystal field parameters B _0 ~2 of the OPPh _3 adducts are much less negative than those of the remaining adducts or that of the base free compound.

机译：三（双（三甲基甲硅烷基）ami基）sa（III）（Sm（btmsa）_3）部分以及已经在室温和低温下记录了双四氢呋喃（4）和部分三（双（二甲基甲硅烷基）part基）tri（III）的双三苯基氧化膦（5）。从获得的光谱中，可以得出潜在的晶体场分裂模式，并通过拟合现象学哈密顿量的自由参数进行模拟。 OPPh _3加合物的晶体场参数B _0〜2的值比其余加合物或无碱化合物的负值小得多。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第8期|共8页
作者
Jank S.; Reddmann H.; Zhang L.; Amberger H.-D.;
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正文语种 eng
中图分类化学;
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Crystal field analyses; N ligands; Optical spectra; Rare-earth compounds;

机译：晶体场分析N配体光谱稀土化合物;

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1. Electronic structures of highly symmetrical compounds of f elements. 45 ~([1]) unusual spectrochemical properties of the triphenylphosphinoxido ligand in the case of mono and bis adducts of homoleptic samarium(III) silylamides [J] . Jank S., Reddmann H., Zhang L., Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第7a8期

机译：f元素高度对称的化合物的电子结构。在均化sa（III）甲硅烷基酰胺的单加合物和双加合物的情况下，三苯基膦氧化配体具有45〜（[1]）的异常光谱化学性质
2. Electronic structures of highly symmetrical compounds of f elements. 41 [1] synthesis, crystal, molecular and electronic structure of a bis(cyclohexylisonitrile) adduct derived from the Tris(bis(trimethylsilyl)amido)erbium(III) moiety and electronic [J] . Jank S, Guttenberger C, Reddmann H, Zeitschrift fur Anorganische und Allgemeine Chemie . 2006,第15期

机译：f元素高度对称的化合物的电子结构。 41 [1]衍生自三（双（三甲基甲硅烷基）氨基）III（III）部分的双（环己基异腈）加合物的合成，晶体，分子和电子结构
3. Electronic structures of highly symmetrical compounds of f elements. 34 - Synthesis and spectroscopic characterization of biscyclohexylisocyanide adducts derived from the tris(bis(trimethylsilyl)amido)lanthanide(III) moiety as well as crystal, molecu [J] . Jank S., Hanss J., Reddmann H., Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第6期

机译：f元素高度对称的化合物的电子结构。 34-衍生自三（双（三（甲基硅烷基）酰胺基）镧系元素（III）部分以及晶体，分子的双环己基异氰化物加合物的合成和光谱表征
4. Theoretical Studies on the Electronic Structures and Spectral Properties of Two Iridium(III) Complexes with Tetraphenylimidodiphosphinate Ligand [C] . Han De-ming, Zhang Gang, Zhao Li-hui International Conference onuture Optical Materials and Circuit Design . 2013

机译：用四苯基咪唑膦配体的两种铱（III）配合物的电子结构和光谱特性的理论研究
5. Crystal structure of a samarium(III) nitrate chain cross-linked by a bis-carbamoylmethylphosphine oxide ligand [O] . Julie A. Stoscup, Richard J. Staples, Shannon M. Biros 2014

机译：双氨基甲酰基甲基氧化膦配体交联的硝酸sa（III）链的晶体结构
6. Synthesis of asymmetrical diaminobis(alkoxo)-bisphenol compounds and their C1-symmetrical mono-ligated titanium(iv) complexes as highly stable highly active antitumor compounds [O] . Gilad Nahari, Edit Y. Tshuva 2021

机译：合成非对称二氨基氨基氨基氨基氨酸（烷氧基氧基氧基） - 苯酚化合物及其C1对称单链钛（IV）复合物，如高稳定的高活性抗肿瘤化合物
7. Electronic structure of organometallic complexes of the f elements XXVIII. Interpretation of the optical and magnetochemical data of a cyclohexylisocyanide adduct derived from tris((eta)(sup 5)-cyclopentadienyl)-samarium(III). [R] . H. Reddmann H. Schultze H. D. Amberger G. V. Shalimoff N. M. Edelstein 1991

机译：f元素XXVIII的有机金属配合物的电子结构。解释衍生自三（η）（sup 5） - 环戊二烯基） - 钐（III）的环己基异氰化物加合物的光学和磁化学数据。

Electronic structures of highly symmetrical compounds of f elements. 45 ~([1]) unusual spectrochemical properties of the triphenylphosphinoxido ligand in the case of mono and bis adducts of homoleptic samarium(III) silylamides

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