A luminescent cage-like complex constructed by bidentate pyridine-containing ligand and silver nitrate

Liu Y.; Yu Y.-H.; Liu Y.-F.; Hou G.-F.; Wang X.-D.; Wen B.; Gao J.-S.

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A luminescent cage-like complex constructed by bidentate pyridine-containing ligand and silver nitrate

机译：由含二齿吡啶的配体和硝酸银构成的发光笼状复合物

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The cage-like complex, Ag_4L_4(NO_3) _4 (1) [L = 1, 4-bis(pyridine-2-ylmethoxy)benzene] was synthesized by the reaction of the flexible bidentate ligand and silver nitrate. It was characterized by elemental analysis, IR spectroscopy, TG, and single-crystal X-ray analysis. Complex 1 is reported as the first cage-like cluster constructed by four nitrate anions bridging two [2+2] macrocycles. A blue luminescent emission and luminescent enhancement effect are observed in complex 1.

机译：通过柔性二齿配体与硝酸银的反应合成了笼状复合物Ag_4L_4（NO_3）_4（1）[L = 1，4-双（吡啶-2-基甲氧基）苯]。通过元素分析，红外光谱，TG和单晶X射线分析对其进行表征。据报道，配合物1是由四个硝酸根阴离子桥接两个[2 + 2]大环构成的第一个笼状簇。在配合物1中观察到蓝色发光和发光增强作用。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2013年第1期|共4页
作者
Liu Y.; Yu Y.-H.; Liu Y.-F.; Hou G.-F.; Wang X.-D.; Wen B.; Gao J.-S.;
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正文语种 eng
中图分类化学;
关键词
Cage-like complexes; Crystal structure; Flexible bidentate ligand; Silver;

机译：笼状复合物;晶体结构;灵活的双齿配体;银;

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1. A luminescent cage-like complex constructed by bidentate pyridine-containing ligand and silver nitrate [J] . Liu Y., Yu Y.-H., Liu Y.-F., Zeitschrift fur Anorganische und Allgemeine Chemie . 2013,第1期

机译：由含二齿吡啶的配体和硝酸银构成的发光笼状复合物
2. Metallosupramolecular Ni2L3 and Ni4L6 complexes of bis-bidentate pyridine-containing ligands: X-ray structures and catalytic proton reduction [J] . Tsang Chui-Shan, Chen Lingjing, Li Lu-Wei, Dalton transactions: An international journal of inorganic chemistry . 2015,第29期

机译：双齿含吡啶配体的金属超分子Ni2L3和Ni4L6配合物：X射线结构和催化质子还原
3. Silver(I) complexes with heterocyclic thiones and tertiary phosphines as ligands. Part 3. Solution behaviour of mononuclear complexes of silver(I) nitrate. The crystal structure of bis(triphenylphosphino)bis(benzoxazoline-2-thione)silver(I) nitrate [J] . McFarlane W., Aslanidis P., Karagiannidis P., Inorganica Chimica Acta . 1998,第2期

机译：以杂环硫酮和叔膦为配体的银（I）配合物。第3部分。硝酸银（I）单核络合物的溶液行为。硝酸双（三苯基膦基）双（苯并恶唑啉-2-硫酮）硝酸银（I）的晶体结构
4. Synthesis, Spectral Characterization and Luminescent Properties of Ternary Rare Earth Nitrates Complexes with 2-Acetylpyridinetris(2-aminoethyl)amine and Pyridine-N-oxide Ligand [C] . Lian-Cai Du International Conference on Material Science, Environmental Science and Computer Science . 2011

机译：三元稀土硝酸盐配合物的合成，光谱表征和发光特性，具有2-乙酰吡啶替辛（2-氨基乙基）胺和吡啶-N-氧化物配体
5. Structural and electronic effects of mono- and bidentate perfluorinated alkoxide ligands in late first-row transition metal complexes. [D] . Cantalupo, Stefanie A. 2013

机译：第一排后期过渡金属络合物中单和双齿全氟烷氧化物配体的结构和电子效应。
6. Silver(I)-directed growth of metal-organic complex nanocrystals with bidentate ligands of hydroquinine anthraquinone-14-diyl diethers as linkers at the water-chloroform interface [O] . Ying Tang, Hui-Ting Wang, Meng Chen, 2014

机译：在水-氯仿界面上以氢醌蒽醌-14-二烷基二醚的双齿配体为连接基的金属-有机复合纳米晶体的银（I）定向生长
7. Solvation effects on the stability of silver(I) complexes with pyridine-containing ligands studied by thermodynamics and DFT methods (vol 46, pg 4689, 2007) [O] . Del Piero Silvia, Fedele Rosalisa, Melchior A, 2008

机译：通过热力学和DFT方法研究了溶剂化对银（I）与含吡啶配体配合物稳定性的影响（第46卷，第4689页，2007）

A luminescent cage-like complex constructed by bidentate pyridine-containing ligand and silver nitrate

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