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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Solvothermal synthesis, crystal structure, and strong luminescence of the first organic-templated europium sulfate chloride
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Solvothermal synthesis, crystal structure, and strong luminescence of the first organic-templated europium sulfate chloride

机译:溶剂热合成,晶体结构和第一个有机模板化硫酸euro氯化物的强发光

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摘要

The first organic amine templated europium sulfate chloride [C _6N_4H_(22)]_(0.5)Cl[Eu(SO_4) 2·H_2O] (1) was synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, TGA, and ICP. Crystal analyses of compound 1 shows a novel inorganic layer constructed from [-Eu-O-S-O-]_n chains. The adjacent chains are connected by sharing the bridging SO_4 ~(2-) groups to generate eight-membered rings. The very strong luminescence in the red light region indicates compound 1 is an excellent candidate for red fluorescent materials.
机译:溶剂热合成第一有机胺模板化硫酸euro氯化物[C _6N_4H_(22)] _(0.5)Cl [Eu(SO_4)2·H_2O](1),并通过单晶X射线衍射,红外光谱, TGA和ICP。化合物1的晶体分析显示由[-Eu-O-S-O-] _ n链构成的新型无机层。相邻的链通过共享桥接SO_4〜(2-)基团连接而生成八元环。红光区域中非常强的发光表明化合物1是红色荧光材料的极佳候选者。

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