Syntheses, Crystal Structures, and Properties of a Salamo-type Tetradentate Chelating Ligand and Its Pentacoordinated Copper(II) Complex

Wen-Kui Dong; Zheng-Kun Wang; Gang Li; Meng-Meng Zhao; Xiu-Yan Dong; Sen-Hua Liu

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Syntheses, Crystal Structures, and Properties of a Salamo-type Tetradentate Chelating Ligand and Its Pentacoordinated Copper(II) Complex

机译：Salamo型四齿螯合配体及其五配位铜（II）配合物的合成，晶体结构和性质

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A Salamo-type ligand 6,6'-diethoxy-2,2'-[1,1'-(ethylenedioxydinitrilo) dimethylidyne]diphenol (H_2L) and its pentacoordinate copper(II) complex [CuL(H_2O)] were synthesized and structurally characterized. The molecule of H_2L is located in a crystallographic inversion center and adopts E configuration with respect to the C=N bond. In the complex [CuL(H_2O)], the Cu~(II) atom has a tetragonally elongated square-pyramidal configuration with donor atoms N_2O_2 forming a perfect basal plane. And an infinite 2D layer supramolecular structure is formed through intermolecular C1-H1A···O5 and C2-H2A···O3 hydrogen bonding interactions.

机译：合成了Salamo型配体6,6'-二乙氧基-2,2'-[1,1'-（亚乙基二氧基二苯并三甲基）二甲基二炔]二酚（H_2L）及其五配位铜（II）配合物[CuL（H_2O）]。表征。 H_2L分子位于晶体学反转中心，并且对于C ＝ N键采用E构型。在配合物[CuL（H_2O）]中，Cu〜（II）原子具有四方伸长的方锥构型，施主原子N_2O_2形成了完美的基面。通过分子间的C1-H1A···O5和C2-H2A···O3的氢键相互作用形成了无限的二维层超分子结构。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2013年第13期|共6页
作者
Wen-Kui Dong; Zheng-Kun Wang; Gang Li; Meng-Meng Zhao; Xiu-Yan Dong; Sen-Hua Liu;
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正文语种 eng
中图分类化学;
关键词
Salamo-type ligand; Copper; Synthesis; Crystal structure; Property;

机译：Salamo型配体;铜;合成;晶体结构;性能;

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1. Syntheses, Crystal Structures, and Properties of a Salamo-type Tetradentate Chelating Ligand and Its Pentacoordinated Copper(II) Complex [J] . Wen-Kui Dong, Zheng-Kun Wang, Gang Li, Zeitschrift fur Anorganische und Allgemeine Chemie . 2013,第12a13期

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Syntheses, Crystal Structures, and Properties of a Salamo-type Tetradentate Chelating Ligand and Its Pentacoordinated Copper(II) Complex

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