Synthesis, structure, and characterization of a microporous metal-organic framework with PtS topology

Zhang Q.-F.; Luo J.-H.; Yuan A.-H.

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Synthesis, structure, and characterization of a microporous metal-organic framework with PtS topology

机译：具有PtS拓扑结构的微孔金属有机骨架的合成，结构和表征

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The microporous metal-organic framework Cd_2(ABTC)(H_ 2O)(DMA)_2·H_2O·3DMA (1) (H_ 4ABTC = 3,3',5,5'-azobenzenetetracarboxylic acid; DMA = N,N'-dimethylacetamide) was prepared by solvothermal reaction and characterized. X-ray structure analysis revealed that compound 1 is a three-dimensional (3D) open framework with 2D channels. The topology is based on a PtS net, constructed of 4-connected rectangular ABTC~(4-) units with 4-connected tetrahedral dinuclear Cd_2(CO_2)_4(H_2O)(DMA)_ 2 secondary building units (SBUs). The solid-state excitation-emission spectra showed that the strongest emission peak is at 403 nm upon excitation at λ = 287 nm.

机译：微孔金属有机骨架Cd_2（ABTC）（H_2O）（DMA）_2·H_2O·3DMA（1）（H_ 4ABTC = 3,3'，5,5'-偶氮苯四甲酸; DMA = N，N'-二甲基乙酰胺通过溶剂热反应制备并表征。 X射线结构分析表明，化合物1是具有2D通道的三维（3D）开放框架。该拓扑基于PtS网络，该网络由4个连接的矩形ABTC〜（4-）单元和4个连接的四面体双核Cd_2（CO_2）_4（H_2O）（DMA）_2个二级建筑单元（SBU）构成。固态激发-发射光谱表明，在λ= 287 nm激发时，最强的发射峰位于403 nm。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2013年第10期|共4页
作者
Zhang Q.-F.; Luo J.-H.; Yuan A.-H.;
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正文语种 eng
中图分类 54;
关键词
Cadmium; Coordination networks; Luminescence; PtS topology;

机译：镉;配位网络;发光;PtS拓扑;

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1. Synthesis, structure, and characterization of a microporous metal-organic framework with PtS topology [J] . Zhang Q.-F., Luo J.-H., Yuan A.-H. Zeitschrift fur Anorganische und Allgemeine Chemie . 2013,第10期

机译：具有PtS拓扑结构的微孔金属有机骨架的合成，结构和表征
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Synthesis, structure, and characterization of a microporous metal-organic framework with PtS topology

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