3D Luminescent Copper(I) Iodide Coordination Polymer Based on Cu4I4 Clusters and an Ethyl-bridging Bis(triazole) Ligand

Dou Ai-Na; Du Yuan-Chao; Chen Qiu-Lu; Luo Kai-Li; Zhang Ce; Zhu Ai-Xin; Li Qiu-Xia

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3D Luminescent Copper(I) Iodide Coordination Polymer Based on Cu4I4 Clusters and an Ethyl-bridging Bis(triazole) Ligand

机译：基于Cu4I4簇和乙基桥联双（三唑）配体的3D发光碘化铜（I）配位聚合物

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摘要

The copper-iodine based coordination polymer [Cu4I2(bmte)](n) (1) [H(2)bmte = 1,2-bis(5-methyl-1H-1,2,4-triazol-3-yl)ethane] was synthesized using cuprous iodide and a flexible 3-substituted, ethyl-bridging bis(triazole) ligand under solvothermal conditions. X-ray diffraction analysis reveals that compound 1 shows a 3D framework containing Cu4I4 clusters and alternating left- and right-handed [Cu(triazole)] helices, which result in a (4,8)-connected fluorite (flu) topological network. Moreover, compound 1 exhibits orange phosphorescence with the emission maxima at 590 nm in the solid state at room temperature.

机译：铜-碘基配位聚合物[Cu4I2（bmte）]（n）（1）[H（2）bmte = 1,2-双（5-甲基-1H-1,2,4-三唑-3-基）在溶剂热条件下，使用碘化亚铜和柔性的3取代乙基桥联双（三唑）配体合成[乙烷]。 X射线衍射分析表明，化合物1显示了一个3D框架，其中包含Cu4I4簇以及交替的左手和右手[Cu（triazole）]螺旋，这导致了一个（4,8）连接的萤石（flu）拓扑网络。此外，化合物1在室温下在固态下表现出橙色磷光，最大发射在590nm。

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2016年第23期|共5页
作者
Dou Ai-Na; Du Yuan-Chao; Chen Qiu-Lu; Luo Kai-Li; Zhang Ce; Zhu Ai-Xin; Li Qiu-Xia;
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正文语种 eng
中图分类化学;
关键词
Copper(I)-iodide complexes; Bis(triazole); Crystal structure; Luminescence;

机译：碘化铜（I）配合物;双（三唑）;晶体结构;发光;

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1. 3D Luminescent Copper(I) Iodide Coordination Polymer Based on Cu4I4 Clusters and an Ethyl-bridging Bis(triazole) Ligand [J] . Dou Ai-Na, Du Yuan-Chao, Chen Qiu-Lu, Zeitschrift fur Anorganische und Allgemeine Chemie . 2016,第13期

机译：基于Cu4I4簇和乙基桥联双（三唑）配体的3D发光碘化铜（I）配位聚合物
2. 3D Luminescent Copper(I) Iodide Coordination Polymer Based on Cu4I4 Clusters and an Ethyl-bridging Bis(triazole) Ligand [J] . Dou Ai-Na, Du Yuan-Chao, Chen Qiu-Lu, Zeitschrift fur Anorganische und Allgemeine Chemie . 2016,第23期

机译：基于Cu4I4簇和乙基桥联双（三唑）配体的3D发光碘化铜（I）配位聚合物
3. 3D Luminescent Copper(I) Iodide Coordination Polymer Based on Cu4I4 Clusters and an Ethyl-bridging Bis(triazole) Ligand [J] . Dou Ai-Na, Du Yuan-Chao, Chen Qiu-Lu, Zeitschrift fur Anorganische und Allgemeine Chemie . 2016,第23期

机译：3D发光铜（I）基于Cu4i4簇的碘化物配位聚合物和乙基桥接双（三唑）配体
4. Synthesis, Structure and Explosive Properties of Copper(II) Chlorate(Ⅶ) Coordination Polymer with 4-Amino-1, 2, 4-Triazole Bridging Ligand [C] . CUDZILO Stanislaw, NITA Marcin Theory and practice of energetic materials . 2009

机译：具有4-氨基-1，2，4，4-三唑桥联配体的氯酸铜（Ⅶ）配位聚合物的合成，结构和爆炸性质
5. Studies into selective fluorination and the coordination chemistry of alkyl iodides and the ligands meso and racemic 1,2-bis(phenylphosphine-oxide)ethane. [D] . Horvath, Michael John. 1994

机译：研究烷基碘与配体的内消旋和外消旋1,2-双（苯基膦氧化物）乙烷的选择性氟化和配位化学。
6. Luminescent Thermochromism of 2D Coordination Polymers Based on Copper(I) Halides with 4-Hydroxythiophenol [O] . Javier Troyano, Josefina Perles, Pilar Amo-Ochoa, -1

机译：卤化铜（I）与4-羟基硫代苯酚的二维配位聚合物的发光热致变色
7. Cuprophilic interactions in luminescent copper(I) clusters with bridging bis(dicyclohexylphosphino)methane and iodide ligands : spectroscopic and structural investigations [O] . Fu WF, Gan X, Che CM, 2004

机译：具有桥联双（二环己基膦基）甲烷和碘化物配体的发光铜（I）团簇中的嗜铜相互作用：光谱学和结构研究

3D Luminescent Copper(I) Iodide Coordination Polymer Based on Cu4I4 Clusters and an Ethyl-bridging Bis(triazole) Ligand

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