A Heteroleptic (E)-1,2-Diaryl-1,2-disilyldistannene without Donor Stabilization [1]

Martin Sturmann; Wolfgang Saak; Karl W. Klinkhammer; Manfred Weidenbruch

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A Heteroleptic (E)-1,2-Diaryl-1,2-disilyldistannene without Donor Stabilization [1]

机译：不含供体稳定作用的（E）-1,2-二芳基-1,2-二甲硅烷基二萘异戊二烯[1]

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The reaction of the stannylene R_2Sn: (R = 2-tBu-4,5,6-Me_3C_6H) with R'_2Sn (R' = Si(SiMe_3)_3) proceeds with substituent exchange to afford the heteroleptic stannylene RR'Sn: which, in the solid state, forms the distannene RR'Sn = SnRR' (7). The X-ray structure analysis of 7 reveals a trans-bent arrangement of the substituents with a large fold angle of 44.9 deg and an Sn-Sn double length of 279.14(4) pm.

机译：亚锡R_2Sn：（R = 2-tBu-4,5,6-Me_3C_6H）与R'_2Sn（R'= Si（SiMe_3）_3）的反应进行取代基交换，得到杂亚锡亚锡RR'Sn：处于固态时，形成二甲苯RR'Sn = SnRR'（7）。对7的X射线结构分析显示，取代基的跨弯排列具有44.9度的大折叠角和279.14（4）pm的Sn-Sn双倍长度。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1999年第12期|共2页
作者
Martin Sturmann; Wolfgang Saak; Karl W. Klinkhammer; Manfred Weidenbruch;
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正文语种 eng
中图分类化学;
关键词
tin; stannylene; multiple bonds;

机译：锡;亚锡;多重键;

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1. A Heteroleptic (E)-1,2-Diaryl-1,2-disilyldistannene without Donor Stabilization [1] [J] . Martin Sturmann, Wolfgang Saak, Karl W. Klinkhammer, Zeitschrift fur Anorganische und Allgemeine Chemie . 1999,第12期

机译：不含供体稳定作用的（E）-1,2-二芳基-1,2-二甲硅烷基二萘异戊二烯[1]
2. Novel heteroleptic stannylenes with intramolecular O,C,O-donor stabilization [J] . Mehring M., Schurmann M., Uhlig F., Organometallics . 2000,第22期

机译：具有分子内O，C，O供体稳定的新型杂多亚锡
3. Structure-property relationship of extended it-conjugation of ancillary ligands with and without an electron donor of heteroleptic Ru(ii) bipyridyl complexes for high efficiency dye-sensitized solar cells [J] . Maqbool Hussain, Ahmed El-Shafei, Ashraful lslam Physical chemistry chemical physics: PCCP . 2013,第21期

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4. DONOR SPECIFIC ANTIBODIES WITH OR WITHOUT POSITIVE C4D STAINING ARE CORRELATED WITH AMR AND/OR BOS IN LUNG TRANSPLANT RECIPIENTS [C] . Marilyn S. Pollack, Deborah J. Levine, Sherry L. Werner, Clinical Histocompatibility Workshop. . 2009

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机译：[M（bpy）2氰基]类型的第8组金属配合物的光化学（M =铁，钌）。杂合铁（II）化合物的光合作用和钌（II）化合物的光电离，或者杂合铁（II）化合物的光辅助合成和钌（II）配合物的光电离。
6. Novel Heteroleptic Ruthenium(II) Complexes with 22′-Bipyridines Containing a Series of Electron-Donor and Electron-AcceptorSubstituents in 44′-Positions: Syntheses Characterizationand Application as Sensitizers for ZnO Nanowire-Based Solar Cells [O] . FernandoF. Salomón, Nadia C. Vega, Teodor Parella, 2020

机译：新型具有22-的异硫钌（II）配合物含有一系列电子供体和电子受体的联吡啶44-位置的取代基：合成表征纳米氧化锌基太阳能电池敏化剂的研究与应用
7. Donor-Acceptor Heteroleptic Open Sandwiches [O] . -1

机译：供体 - 受体异悬的三明治

A Heteroleptic (E)-1,2-Diaryl-1,2-disilyldistannene without Donor Stabilization [1]

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