Hydrothermal Synthesis of Chiral Metal(II) Phosphinates Derived from Camphor

Beckmann J; Duthie A; Ruttinger R; Schwich T

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Hydrothermal Synthesis of Chiral Metal(II) Phosphinates Derived from Camphor

机译：樟脑衍生的手性金属膦酸酯的水热合成

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The diastereoselective synthesis of bis(3-endo-camphoryl)-phosphinic acid (1) and its 2-bornen-2-yl ester 2 from the reaction of lithium camphor enolate with phosphorus trichloride and the hydrothermal synthesis of three chiral. molecular metal(II) phosphinates of the type M(O2PR2)(2) center dot 2R(2)P(O)OH [M = Co (3); Ni (4); Ph (5); R = 3-endo-camphoryl] from the reaction of 1 with metal(II) acetates or nitrates is described. The molecular structures of 1-5 are reported.

机译：由樟脑烯醇酸锂与三氯化磷反应和水热合成三个手性化合物，合成非对映选择性的双（3-内-樟脑基）-次膦酸（1）及其2-冰片-2-基酯2。 M（O2PR2）（2）中心点2R（2）P（O）OH类型的分子金属（II）次膦酸盐[M = Co（3）;镍（4）; Ph（5）;描述了R与3-金属乙酸盐或硝酸盐反应生成的R ＝ 3-内-樟脑酰基。报告了1-5的分子结构。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第10期|共8页
作者
Beckmann J; Duthie A; Ruttinger R; Schwich T;
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正文语种 eng
中图分类化学;
关键词
Hydrothermal synthesis; Phosphinate ligands; Chirality; Terpenoids;

机译：水热合成;膦酸酯配体;色度;类萜;

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1. Hydrothermal Synthesis of Chiral Metal(II) Phosphinates Derived from Camphor [J] . Beckmann J, Duthie A, Ruttinger R, Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第9a10期

机译：樟脑衍生的手性金属膦酸酯的水热合成
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机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。
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7. Chiral heterocyclic ligands. XII. Metal complexes of a pyrazine ligand derived from camphor [O] . Fitchett C.M., Steel P.J. 2006

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8. Chiral Synthesis via Organoboranes. 18. Selective Reductions. 43. Diisopinocampheylchloroborane as an Excellent Chiral Reducing Reagent for the Synthesis of Halo Alcohols of High Enantiomeric Purity. A Highly Enantioselective Synt [R] . Srebnik, M., Ramachandran, P. V., Brown, H. C. 1988

机译：有机硼烷的手性合成。 18.选择性削减。 43. Diisopinocampheylchloroborane作为一种优良的手性还原剂，用于合成高对映体纯度的卤代醇。高度对映选择性合成

Hydrothermal Synthesis of Chiral Metal(II) Phosphinates Derived from Camphor

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