...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Effect of the length of fatty acid ligands on lead(II) complexes based on a 1,10-phenanthroline derivative
【24h】

Effect of the length of fatty acid ligands on lead(II) complexes based on a 1,10-phenanthroline derivative

机译：脂肪酸配体长度对基于1,10-菲咯啉衍生物的铅（II）配合物的影响

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Two new PbII metal-organic coordination polymers [Pb(3-pdip)(glu)]·H_2O (1) and [Pb(3-pdip)_2(odc)] ·2H_2O (2) [3-pdip = 2-(3-pyridine)imidazo[4,5-f]1,10- phenanthroline, H_2glu = glutaric acid, H_2odc = octanedioic acid], were synthesized by hydrothermal reactions of varying fatty acid ligands, and structurally characterized by single-crystal X-ray diffraction. Complex 1 exhibits a one dimensional (1D) chain structure, in which 3-pdip ligands are attached to one side of the 1D chain. Complex 2 exhibits also a 1D chain structure, in which some paired 3-pdip ligands are affiliated on both sides of the 1D chain. In the title complexes, the π-π stacking and hydrogen-bonding interactions extend the 1D chain into a 3D supramolecular framework, respectively. The structural differences between the title complexes indicate the importance of fatty acid length for the creation of molecular architectures. Moreover, the thermal and fluorescence properties of title complexes are also reported.
机译：两种新的PbII金属-有机配位聚合物[Pb（3-pdip）（glu）]·H_2O（1）和[Pb（3-pdip）_2（odc）]·2H_2O（2）[3-pdip = 2-（通过各种脂肪酸配体的水热反应合成3-吡啶）咪唑并[4,5-f] 1,10-菲咯啉，H_2glu =戊二酸，H_2odc =辛二酸]，并通过单晶X射线表征结构衍射。配合物1表现出一维（1D）链结构，其中3-pdip配体连接到1D链的一侧。配合物2还显示1D链结构，其中一些成对的3-pdip配体连接在1D链的两侧。在标题配合物中，π-π堆积和氢键相互作用分别将1D链延伸到3D超分子框架中。标题复合物之间的结构差异表明脂肪酸长度对于创建分子结构的重要性。此外，还报道了标题复合物的热和荧光性质。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号