首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis and characterization of triphenyltin(IV) carboxylates with isophthalic acid and benzoic acid derivatives: X-ray crystal structures of 1D supramolecular chains
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Synthesis and characterization of triphenyltin(IV) carboxylates with isophthalic acid and benzoic acid derivatives: X-ray crystal structures of 1D supramolecular chains

机译:间苯二甲酸和苯甲酸衍生物的羧酸三苯锡(IV)的合成与表征:一维超分子链的X射线晶体结构

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摘要

The reaction of triphenyltin(IV) hydroxide with the isophthalic acid and benzoic acid derivatives, 5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-isophthalic acid (H_2L~1) and 4-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)- benzoic acid (HL_2) yielded the complexes [(SnPh_3) _2L~1] (1) and [(SnPh_3)L~2] (2). All complexes were characterized by elemental analysis and FT-IR and NMR (~1H, ~(13)C, ~(119)Sn) spectroscopy. Interestingly, the supramolecular structures of 1 and 2 are found to consist of 1D molecular chains built up by intermolecular C-H?O hydrogen bonds. Their thermal stabilities were also investigated.
机译:氢氧化三苯基锡(IV)与间苯二甲酸和苯甲酸衍生物,5-(1,3-二氧代-1,3-二氢-异吲哚-2-基)-间苯二甲酸(H_2L〜1)和4-( 1,3-二氧代-1,3-二氢-异吲哚-2-基)-苯甲酸(HL_2)生成络合物[(SnPh_3)_2L〜1](1)和[(SnPh_3)L〜2](2) 。所有的络合物都通过元素分析,FT-IR和NMR(〜1H,〜(13)C,〜(119)Sn)光谱进行表征。有趣的是,发现1和2的超分子结构由通过分子间的C-H2O氢键建立的一维分子链组成。还研究了它们的热稳定性。

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