Synthesis, structures, and properties of two helical structures from rigid carboxylate ligand and flexible N-bridging ligands

Li X.; Zhao W.; Zhang Y.; Tan J.; Lu Y.; Feng X.; Yang X.

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Synthesis, structures, and properties of two helical structures from rigid carboxylate ligand and flexible N-bridging ligands

机译：刚性羧酸盐配体和柔性N桥桥接配体的两个螺旋结构的合成，结构和性质

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Two novel coordination polymers based on mixed ligands, [Zn(dpb)(bdc)(H _2O)] _n (1) and [Cd(dpb)(bbdc)(H _2O)(DMF)] _n (2) [dpb = 1, 4-bis(pyridin-3-ylmethoxy) benzene, H _2bdc = 1, 4-benzenedicarboxylate, H _2bbdc = 4, 4'-dibenzenedicarboxylate], were synthesized under hydrothermal conditions. Compound 1 forms meso-helical chain and shows three fold interpenetrating architecture with 4-connected net {6 6} diamond topology. Compound 2 is a left- and right-handed helical layer, which are interacted by π-π stacking interactions to construct a 3D framework. The luminescent properties of the compounds are discussed.

机译：基于混合配体的两种新型配位聚合物[Zn（dpb）（bdc）（H _2O）] _n（1）和[Cd（dpb）（bbdc）（H _2O）（DMF）] _n（2）[dpb =在水热条件下合成了1，4-双（吡啶-3-基甲氧基）苯，H _2bdc = 1，4-苯二甲酸，H _2bbdc = 4，4'-二苯二甲酸]。化合物1形成中螺旋链，并显示三重互穿结构，具有4个连接的净{6 6}菱形拓扑。化合物2是左旋和右旋螺旋层，它们通过π-π堆叠相互作用进行交互以构建3D框架。讨论了化合物的发光性质。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第5期|共6页
作者
Li X.; Zhao W.; Zhang Y.; Tan J.; Lu Y.; Feng X.; Yang X.;
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正文语种 eng
中图分类化学;
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Cadmium; Helical structure; Luminescence; Porous framework; Three-fold interpenetrating architecture; Zinc;

机译：镉螺旋结构发光多孔结构三重互穿结构锌;

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1. Synthesis, structures, and properties of two helical structures from rigid carboxylate ligand and flexible N-bridging ligands [J] . Li X., Zhao W., Zhang Y., Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第5期

机译：刚性羧酸盐配体和柔性N桥桥接配体的两个螺旋结构的合成，结构和性质
2. Solvent-induced synthesis of cobalt(II) coordination polymers based on a rigid ligand and flexible carboxylic acid ligands: syntheses, structures and magnetic properties [J] . Wang Ting, Zhang Chuanlei, Ju Zemin, Dalton transactions: An international journal of inorganic chemistry . 2015,第15期

机译：溶剂诱导的基于刚性配体和柔性羧酸配体的钴（II）配位聚合物的合成：合成，结构和磁性
3. Synthesis, Structures, and Fluorescent Properties of Three Cobalt-Based Coordination Polymers with a Rigid Tripodal Carboxylate Ligand [J] . Liu Xiao-Bin, Xiao Zhen-Yu, Huang Ao, Zeitschrift fur Anorganische und Allgemeine Chemie . 2016,第1期

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4. Synthesis and Structures of Disilanes Containing Two Highly Coordinate Silicon Atoms Bridged by Carboxylate Ligands [C] . Yasuhiro Shinozaki, Norikiyo Nakagawa, Naokazu Kano, Symposium on Organometallic Chemistry . 2004

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5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

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Synthesis, structures, and properties of two helical structures from rigid carboxylate ligand and flexible N-bridging ligands

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