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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis and characterization of energetic salts of the (C _4N _(12) ~(2-)) dianion
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Synthesis and characterization of energetic salts of the (C _4N _(12) ~(2-)) dianion

机译：（C _4N _（12）〜（2-））双价阴离子的高能盐的合成与表征

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摘要

3, 6-Bis(tetrazol-5-yl)-1, 2, 4, 5-tetrazine is a nitrogen-rich energetic compound readily prepared and a strong dibasic acid. By the reaction with energetic bases such including hydroxylamine, triaminoguanidine, hydrazine, and diaminourea, multiple ionic energetic materials were prepared and characterized for the first time. Both chemical (multinuclear NMR, Infrared, Raman, MS, etc) as well as explosive (Impact, Friction, Static sensitivities) properties are reported. The materials prepared, with the exception of the silver salt, which is a primary explosive, fall into the classification of low-sensitivity energetic materials due to desensitizing hydration waters. Calculated explosive performances using the EXPLO5 computer code are also reported.
机译：3，6-双（四唑-5-基）-1、2、4、5-四嗪是一种易于制得的富氮高能化合物，也是一种强二元酸。通过与高能碱（包括羟胺，三氨基胍，肼和二氨基脲）反应，首次制备并表征了多种离子高能材料。化学（多核NMR，红外，拉曼，MS等）和爆炸物（抗冲击，摩擦，静态敏感性）特性均已报道。除了作为主要炸药的银盐以外，所制得的材料由于对水合水不敏感而属于低灵敏度含能材料。还报告了使用EXPLO5计算机代码计算出的爆炸性能。

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