Synthesis, structure, and photoluminescent properties of a new 3D metal-organic framework with unusual Ag ~I chains

Wang J.-J.; Cao P.-X.; Zhang M.-L.; Gao L.-J.; Hou X.-Y.

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Synthesis, structure, and photoluminescent properties of a new 3D metal-organic framework with unusual Ag ~I chains

机译：具有异常Ag〜I链的新型3D金属有机骨架的合成，结构和光致发光特性

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A new 3D metal-organic framework {[Ag _4(btc)(bix) _2]·H _2O} _n (1) [H _4btc = biphenyl-2, 2',4, 4'-tetracarboxylic acid, bix = 1, 4-bis(imidazol-1-ylmethyl) benzene] was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared (IR) spectroscopy, thermal gravimetric analysis (TGA), and luminescence studies. The most remarkable structural feature of 1 is that the 1D chain and 2D network interpenetrated structures are further linked by parallel aligned 1D Ag ~I chains to generate 3D metal-organic framework.

机译：新的3D金属有机框架{[Ag _4（btc）（bix）_2]·H _2O} _n（1）[H _4btc =联苯-2，2'，4，4'-四羧酸，bix = 1，在水热条件下合成了4-双（咪唑-1-基甲基）苯，并通过单晶X射线衍射，红外（IR）光谱，热重分析（TGA）和发光研究对其进行了表征。 1的最显着结构特征是1D链和2D网络互穿结构通过平行排列的1D Ag〜I链进一步连接在一起，从而生成3D金属有机骨架。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第10期|共4页
作者
Wang J.-J.; Cao P.-X.; Zhang M.-L.; Gao L.-J.; Hou X.-Y.;
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正文语种 eng
中图分类化学;
关键词
Ag ? Ag interactions; Biphenyl-2; 2′; 4; 4′- tetracarboxylic acid; Metal-organic framework; Silver;

机译：银？ Ag相互作用;联苯-2;2';4;4'-四羧酸;金属有机骨架;银;

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1. Synthesis, structure, and photoluminescent properties of a new 3D metal-organic framework with unusual Ag ~I chains [J] . Wang J.-J., Cao P.-X., Zhang M.-L., Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第10期

机译：具有异常Ag〜I链的新型3D金属有机骨架的合成，结构和光致发光特性
2. Two 3D Zn-II Metal-Organic Frameworks with 3-and 8-Fold Interpenetration: Syntheses, Structures, Photodegradation, and Photoluminescent Properties [J] . Fan Chuan-Bin, Meng Xiang-Min, Fan Yu-Hua, Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry . 2017,第3期

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4. Solvothermal synthesis, structure, fluorescence and magnetism properties of a novel 3D metal-organic framework based on tetranuclear copper secondary building units [C] . Lei Wu, Ming Xue, Gerald Chaplais International Conference on Materials and Products Manufacturing Technology . 2014

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5. Hydrogen storage in metal-organic frameworks: An investigation of structure-property relationships. [D] . Rowsell, Jesse. 2005

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6. Four Mixed-Ligand Zn(II) Three-Dimensional Metal-Organic Frameworks: Synthesis, Structural Diversity, and Photoluminescent Property [O] . Chih-Chieh Wang, Szu-Yu Ke, Chia-Wen Cheng, 2011

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7. Four Mixed-Ligand Zn(II) Three-Dimensional Metal-Organic Frameworks: Synthesis, Structural Diversity, and Photoluminescent Property [O] . Chih-Chieh Wang, Szu-Yu Ke, Chia-Wen Cheng, 2017

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Synthesis, structure, and photoluminescent properties of a new 3D metal-organic framework with unusual Ag ~I chains

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