On the rare earth metal bismuthide oxides RE _2BiO _2 (RE = Nd, Tb, Dy, Ho)

Nuss J.; Jansen M.

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On the rare earth metal bismuthide oxides RE _2BiO _2 (RE = Nd, Tb, Dy, Ho)

机译：在稀土金属铋氧化物RE _2BiO _2（RE = Nd，Tb，Dy，Ho）上

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A series of new RE _2BiO _2 compounds (RE = Nd, Tb, Dy, Ho) has been synthesized from elemental bismuth, REBi, and RE _2O _3 in all-solid state reactions in sealed tantalum ampoules at 1770 K. The dark grey metallic compounds adopt the anti-ThCr _2Si _2 type of structure (I4/mmm, tI10), according to X-ray single crystal structure analysis. As a main structural feature, there are PbO analogous slabs, [REO] ~+, and 4 ~4 nets of Bi ~(2-) anions, alternately stacked along the c-axis.

机译：在1770 K密封的钽安瓿瓶中，在全固态反应中，由元素铋，REBi和RE _2O _3合成了一系列新的RE _2BiO _2化合物（RE = Nd，Tb，Dy，Ho）。根据X射线单晶结构分析，这些化合物采用抗ThCr _2Si _2型结构（I4 / mmm，tI10）。作为主要结构特征，有类似PbO的平板，[REO]〜+和4〜4个Bi〜（2-）阴离子的网，它们沿c轴交替堆积。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第4期|共3页
作者
Nuss J.; Jansen M.;
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正文语种 eng
中图分类化学;
关键词
Bismuthide oxides; Rare earths; Solid-state reactions; Solid-state structures; X-ray diffraction;

机译：氧化铋;稀土;固相反应;固相结构;X射线衍射;

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1. On the rare earth metal bismuthide oxides RE _2BiO _2 (RE = Nd, Tb, Dy, Ho) [J] . Nuss J., Jansen M. Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第3a4期

机译：在稀土金属铋氧化物RE _2BiO _2（RE = Nd，Tb，Dy，Ho）上
2. Coordination Cluster Nuclearity Decreases with Decreasing Rare Earth Ionic Radius in 1:1 Cr/Ln N-Butyldiethanolamine Compounds: A Journey across the Lanthanide Series from (Cr4La4)-La-III-(Cr4Tb4)-Tb-III via (Cr3Dy3)-Dy-III and (Cr3Ho3)-Ho-III to (Cr2Er2)-Er-III-(Cr2Lu2)-Lu-III [J] . Rinck Julia, Lan Yanhua, Anson Christopher E., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2015,第7期

机译：1：1 Cr / Ln N-丁基二乙醇胺化合物中的配位簇核原子随着稀土离子半径的减小而减小：从（Cr4La4）-La-III-（Cr4Tb4）-Tb-III到（Cr3Dy3）-Dy跨越镧系元素的旅程-III和（Cr3Ho3）-Ho-III至（Cr2Er2）-Er-III-（Cr2Lu2）-Lu-III
3. Coordination Cluster Nuclearity Decreases with Decreasing Rare Earth Ionic Radius in 1:1 Cr/Ln N-Butyldiethanolamine Compounds: A Journey across the Lanthanide Series from (Cr4La4)-La-III-(Cr4Tb4)-Tb-III via (Cr3Dy3)-Dy-III and (Cr3Ho3)-Ho-III to (Cr2Er2)-Er-III-(Cr2Lu2)-Lu-III [J] . Rinck Julia, Lan Yanhua, Anson Christopher E., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2015,第7期

机译：1：1 Cr / Ln N-丁基二乙醇胺化合物中的配位簇核原子随着稀土离子半径的减小而减小：从（Cr4La4）-La-III-（Cr4Tb4）-Tb-III到（Cr3Dy3）-Dy跨越镧系元素的旅程-III和（Cr3Ho3）-Ho-III至（Cr2Er2）-Er-III-（Cr2Lu2）-Lu-III
4. Under Pressure: Synthesis and Crystal Structure of the Rare-Earth Metal(III) Hydroxide Oxidotungstates(VI) RE(OH)WO4 (RE = Dy and Ho) [C] . Katharina V. Porn, Thomas Schleid, Ingo Hartenbach Rare Earth Research Conference . 2019

机译：在压力下：稀土金属（III）氢氧化物氧化钨酸盐（VI）Re（OH）WO4（RE = DY和HO）的合成和晶体结构
5. A KINETIC STUDY OF THE OXIDATION OF RARE-EARTH METALS, SOLUBILITY OF RARE-EARTH METALS IN THEIR NITRIDES, AND INFRARED STUDIES OF SOME RARE-EARTH COMPOUNDS [D] . VORRES, KARL SPYROS. 1958

机译：稀土金属的氧化，稀土金属在氮化物中的溶解度的动力学研究以及某些稀土化合物的红外研究
6. Electrochemical Recovery and Behaviors of Rare Earth (La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm and Yb) Ions on Ni Sheets [O] . Min Hee Joo, So Jeong Park, Sung Min Hong, 2020

机译：稀土电化学回收和行为（LaCePrNdSm欧盟GdTbDyHoERTm和Yb）离子在Ni纸上
7. Crystal fields in Sc, Y, and the heavy-rare-earth metals Tb, Dy, Ho, Er, Tm, and Lu [O] . Touborg P. 1977

机译：sc，Y和重稀土金属Tb，Dy，Ho，Er，Tm和Lu中的晶体场
8. Dissociation Energies of Diatomic Rare Earth Molecules Dy2, Ho2, Er2, Tm2, and Yb2 [R] . Lin, S. S., Kant, A. 1971

机译：双原子稀土分子Dy2，Ho2，Er2，Tm2和Yb2的解离能

On the rare earth metal bismuthide oxides RE _2BiO _2 (RE = Nd, Tb, Dy, Ho)

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