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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >|(C _6N _4H _(21)) _2|[Ge _7O _(14)F _6]: A new germanate compound constructed from alternately stacked pseudo triple-sheet layers
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|(C _6N _4H _(21)) _2|[Ge _7O _(14)F _6]: A new germanate compound constructed from alternately stacked pseudo triple-sheet layers

机译：|（C _6N _4H _（21））_2 | [Ge _7O _（14）F _6]：一种由交替堆叠的伪三层板层构成的新型锗酸盐化合物

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摘要

A novel layered germanate compound, |(C _6N _4H _(21)) _2|[Ge _7O _(14)F _6] (JU-86, JU = Jilin University), was solvothermally synthesized. Its structure consists of 4.6-net sheets built up from dissymmetric 8 ~3 building units. Different from those found in several metal phosphate compounds, half of the 4.6-net sheets in JU-86 are constructed from right-handed 8 ~3 building units and the other half are constructed from left-handed ones. Right-handed and left-handed 4.6-net sheets are stacked alternately in JU-86. Each 4.6-net sheet is sandwiched by two layers of protonated tris(2-aminoethyl)amine (tren) molecules to form an unusual pseudo triple-sheet layer through hydrogen-bonding interactions. No hydrogen bonds are found between different pseudo triple-sheet layers
机译：溶剂热合成了新型层状锗酸盐化合物|（C _6N _4H _（21））_2 | [Ge _7O _（14）F _6]（JU-86，JU =吉林大学）。它的结构包括由不对称的8〜3个建筑单元构成的4.6网片。与在几种金属磷酸盐化合物中发现的结构不同，JU-86的4.6网片中的一半由右手8〜3个建筑单元构成，另一半由左手建筑。在JU-86中，右手和左手4.6净纸交替堆叠。每个4.6网片被两层质子化的三（2-氨基乙基）胺（tren）分子夹在中间，通过氢键相互作用形成不寻常的伪三片层。在不同的伪三层片层之间未发现氢键

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