Pyridyl-dicarboxylate tuned cadmium(II) complexes and their fluorescence emission properties

Hu J.; Zhao Z.; Zhao D.; Chen S.; Zhao J.; Zhao H.

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Pyridyl-dicarboxylate tuned cadmium(II) complexes and their fluorescence emission properties

机译：吡啶基二羧酸盐调谐的镉（II）配合物及其荧光发射特性

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To investigate the effect of organic anions on coordination frameworks, the complexes [Cd(2, 6-pydc)(bibix)_2(H_2O)_2] n (1) and {[Cd_4(2, 5-pydc)_4(bibix) _4(H_2O)_4](H_2O)_8} n (2) were isolated by the reactions of 1-{4-[(1H-benzoimidazol-1-yl) methyl]benzyl}-1H-benzoimidazole (bibix) and two distinct pyridyl-dicarboxylates as organic anions with d~(10) metal salts. In the resulting structures, bibix adopts different coordination modes affected by the aromatic anions, which have distinct geometric structure and bonding modes. Thus, complex 1 has a 1D chain structure, whereas complex 2 has a 2D architecture. Both complexes 1 and 2 have a strong fluorescence emission, which may be tentatively assigned to metal-perturbed intraligand interactions

机译：为了研究有机阴离子对配位骨架的影响，配合物[Cd（2，6-pydc）（bibix）_2（H_2O）_2] n（1）和{[Cd_4（2，5-pydc）_4（bibix）通过1- {4-[（1H-苯并咪唑-1-基）甲基]苄基} -1H-苯并咪唑（bibix）的反应分离出_4（H_2O）_4]（H_2O）_8} n（2）吡啶基二羧酸盐与d〜（10）金属盐一起作为有机阴离子。在得到的结构中，bibix采用受芳香族阴离子影响的不同配位模式，它们具有独特的几何结构和键合模式。因此，复合体1具有一维链结构，而复合体2具有2D体系结构。配合物1和2都具有很强的荧光发射，可以暂时归因于金属干扰的配体内相互作用

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2013年第5期|共5页
作者
Hu J.; Zhao Z.; Zhao D.; Chen S.; Zhao J.; Zhao H.;
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正文语种 eng
中图分类化学;
关键词
Cadmium; Fluorescence; N; O ligands; Organic-inorganic hybrid composites;

机译：镉;荧光;N;O配体;有机-无机杂化复合材料;

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1. Pyridyl-dicarboxylate tuned cadmium(II) complexes and their fluorescence emission properties [J] . Hu J., Zhao Z., Zhao D., Zeitschrift fur Anorganische und Allgemeine Chemie . 2013,第5期

机译：吡啶基二羧酸盐调谐的镉（II）配合物及其荧光发射特性
2. Copper(II), Zinc(II), and Cadmium(II) Formylbenzoate Complexes: Reactivity and Emission Properties [J] . Jitendra Nath, Arup Tarai, Jubaraj B. Baruah ACS Omega . 2019,第19期

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3. Syntheses, characterization, X-ray crystal structures and emission properties of copper(II), zinc(II) and cadmium(II) complexes of pyridyl-pyrazole derived Schiff base ligand - Metal selective ligand binding modes [J] . Das K., Mandal T.N., Roy S., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第15期

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4. Synthesis and Fluorescence Properties of New Europium (III) and Terbium (III) Complexes with N-(3-methoxyl-phenyl)ketoacetamide [C] . Xi-Shi Tai International Conference on Material Science, Environmental Science and Computer Science . 2011

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机译：铜（II），锌（II）和镉（II）甲苯苯甲酸酯复合物：反应性和排放性能

Pyridyl-dicarboxylate tuned cadmium(II) complexes and their fluorescence emission properties

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