Synthesis and Characterization of Copper(I) Halide Complexes with N-(2,6-Diisopropylphenyl)-N′-benzoylthiourea: Monomeric, Dimeric, and Cage Structures

Xiao-Ya Zhao; Cheng-Ben Zhu; Hai-Pu Li; Ying Yang; Herbert W. Roesky

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Synthesis and Characterization of Copper(I) Halide Complexes with N-(2,6-Diisopropylphenyl)-N′-benzoylthiourea: Monomeric, Dimeric, and Cage Structures

机译：具有N-（2,6-二异丙基苯基）-N'-苯甲酰基硫脲的卤化铜（I）配合物的合成和表征：单体，二聚体和笼型结构

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The N-(2,6-diisopropylphenyl)-N′-benzoylthiourea ligand (shown as L) (1) was synthesized and characterized. Reactions of 1 with CuCl_2 and CuBr_2 afforded the monomeric L_2CuCl (2) and dimeric [LBrCu(μ-L)]_2 (3), respectively, due to the reduction of Cu~(II). The reaction of 1 and CuCl gave the same product L_2CuCl (2), while the treatment of 1 with CuBr led to the formation of a rare example of adamantanoid cage (LCu)_2(μ-L)_2Cu_2(μ-Br)_4 (4) containing enantiomeric couple. The product of 1 and CuI was found to be dimeric [LICu(μ-L)]_2 (5), which is isomorphous to 3. All compounds obtained were fully characterized by elemental analysis, IR, ~1H NMR and ~(13)C NMR spectroscopy, and single-crystal X-ray diffraction.

机译：合成并表征了N-（2,6-二异丙基苯基）-N'-苯甲酰基硫脲配体（显示为L）（1）。 1与CuCl_2和CuBr_2的反应分别生成了单体L_2CuCl（2）和二聚体[LBrCu（μ-L）] _ 2（3），这是由于Cu〜（II）的还原。 1与CuCl的反应产生相同的产物L_2CuCl（2），而用CuBr处理1导致形成金刚烷类笼（LCu）_2（μ-L）_2Cu_2（μ-Br）_4（ 4）含有对映体对。发现1和CuI的产物为二聚体[LICu（μ-L）] _ 2（5），同构为3。通过元素分析，IR，〜1H NMR和〜（13）充分表征所有获得的化合物。 1 H NMR光谱和单晶X射线衍射。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2014年第9期|共8页
作者
Xiao-Ya Zhao; Cheng-Ben Zhu; Hai-Pu Li; Ying Yang; Herbert W. Roesky;
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正文语种 eng
中图分类化学;
关键词
Acylthiourea; Copper(I) halides; S ligands; Cage compounds;

机译：酰基硫脲;卤化铜;S配体;笼式化合物;

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Synthesis and Characterization of Copper(I) Halide Complexes with N-(2,6-Diisopropylphenyl)-N′-benzoylthiourea: Monomeric, Dimeric, and Cage Structures

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