cyanide-Bridged Tetranuclear (RE2Fe2III)-Fe-III (RE = Y, Tb, Dy) Molecular Squares with 2,2 ':6 ',2 ''-Terpyridine as a capping Ligand

Zhou Hu; Yu Deng-Yong; Zhou Hong-Bo; Yuan Ai-Hua

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cyanide-Bridged Tetranuclear (RE2Fe2III)-Fe-III (RE = Y, Tb, Dy) Molecular Squares with 2,2 ':6 ',2 ''-Terpyridine as a capping Ligand

机译：氰化物桥连的四核（RE2Fe2III）-Fe-III（RE = Y，Tb，Dy）分子正方形，带有2,2'：6'，2'-三联吡啶作为封端配体

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Self-assembly reaction between hydrated lure-earth (RE) nitrates RE,(NO3)(3)center dot 6H(2)O with K3Fe(CN)(6) in H2O/DMF solution by employing the tridentate ligand 2,2':6',2"-terpyridine (terpy) as a capping ligand has yielded three cyanide-bridged compounds [RE(terpy)(DMF)(H2O)(2)]Fe(CN)(6)]center dot 6H(2)O [RE = Y (1), Tb (2), Dy (3)]. FT-IR spectra confirmed the presence of terpy ligands and cyanide. groups in compounds 1-3. Single-crystal X-ray structural analysis indicated that these compounds are isomorphous and adopt neutral [RE2Fe2] molecular squares, which are further linked through hydrogen bonding interactions to generate a three-dimensional supramolecular network. Magnetic susceptibility measurements revealed that significant- single ion magnetic anisotropy dominates the properties of these compounds.

机译：通过使用三齿配体2,2'在H2O / DMF溶液中水合诱饵硝酸（RE）硝酸盐RE，（NO3）（3）中心点6H（2）O与K3Fe（CN）（6）之间的自组装反应：6'，2“-吡啶（封端）作为封端配体产生了三种氰化物桥接的化合物[RE（terpy）（DMF）（H2O）（2）] Fe（CN）（6）]中心点6H（2 O [RE = Y（1），Tb（2），Dy（3）]。FT-IR光谱证实了化合物1-3中存在叔配体和氰基。单晶X射线结构分析表明这些化合物是同构的，并采用中性[RE2Fe2]分子方格，它们通过氢键相互作用进一步连接以生成三维超分子网络，磁化率测量表明，显着的单离子磁各向异性主导了这些化合物的性能。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2015年第5期|共5页
作者
Zhou Hu; Yu Deng-Yong; Zhou Hong-Bo; Yuan Ai-Hua;
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正文语种 eng
中图分类化学;
关键词
Hexacyanometalates; Rare-earth; Molecular square; Magnetic properties;

机译：六价金属酸盐;稀土;分子正方形;磁性;

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1. cyanide-Bridged Tetranuclear (RE2Fe2III)-Fe-III (RE = Y, Tb, Dy) Molecular Squares with 2,2 ':6 ',2 ''-Terpyridine as a capping Ligand [J] . Zhou Hu, Yu Deng-Yong, Zhou Hong-Bo, Zeitschrift fur Anorganische und Allgemeine Chemie . 2015,第5期

机译：氰化物桥连的四核（RE2Fe2III）-Fe-III（RE = Y，Tb，Dy）分子正方形，带有2,2'：6'，2'-三联吡啶作为封端配体
2. Planar tetranuclear dy(III) single-molecule magnet and its Sm(III), Gd(III), and Tb(III) analogues encapsulated by salen-type and β-diketonate ligands [J] . Yan P.-F., Lin P.-H., Habib F., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第15期

机译：平面四核dy（III）单分子磁体及其Sal（III），Gd（III）和Tb（III）类似物被Salen型和β-二酮配体封装
3. Synthesis, characterization and luminescence properties of Ln~(III) (Ln = Eu, Tb, Ce, Sm, Dy) complexes containing a terpyridine ligand and a 3d-4f type conjugated terpyridine-alkyne bridging Eu~(III)-Co~0 carbonyl cluster complex [J] . Bao-Hua Zhu, Yan-Hong Liu, Xue-Yan Jin, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2014,第Null期

机译：含吡啶吡啶配体和3d-4f型共轭吡啶吡啶炔桥接Eu〜（III）-Co〜0的Ln〜（III）（Ln = Eu，Tb，Ce，Sm，Dy）配合物的合成，表征和发光性质羰基簇复合物
4. Spin Crossover in Cyanide-Bridged {Fe~(III)_2Fe~(II)_2} Tetranuclear Cluster with Chiral Ligand [C] . Junqiu Li, Kanegawa Shinji, Osamu Sato 日本化学会春季年会講演予稿集 . 2018

机译：氰化物桥接{Fe〜（III）_2FE〜（II）_2}与手性配体的四核簇旋转交叉
5. (2,2',2''-terpyridine)platinum(II) complexes of phenylcyanamide and 1,4-dicyanamido-2,5-dimethylbenzene ligands [D] . Al-mutlaq, Fahad A. I. 2000

机译：苯甲酰胺和1,4-二氰胺基-2,5-二甲基苯配体的（2,2'，2''-吡啶）铂（II）配合物
6. Ultra-high molecular weight linear coordination polymers with terpyridine ligands [O] . Reece W. Lewis, Nino Malic, Kei Saito, 2019

机译：具有三联吡啶配体的超高分子量线性配位聚合物
7. Multi-Step Phase Transition Based on Intramolecular Electron Transfers in a Cyanide-Bridged Tetranuclear Molecular Square [O] . Masayuki NIHEI 2012

机译：基于分子内电子转移在氰化物桥接四核分子正方形中的多步相转变

cyanide-Bridged Tetranuclear (RE2Fe2III)-Fe-III (RE = Y, Tb, Dy) Molecular Squares with 2,2 ':6 ',2 ''-Terpyridine as a capping Ligand

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