Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)(2)]BF4

Boettcher Hans-Christian; Mies Thomas; Mayer Peter

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)(2)]BF4

【24h】

Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)(2)]BF4

机译：反式[IrCl（NO）（PtBu2H）（2）] BF4的合成及分子结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The synthesis and structural characterization of trans-[IrCl(NO)(PtBu2H)(2)]BF4 (1) is reported. The title compound was prepared in good yield in the reaction of in situ-prepared trans-[IrCl(coe)(PtBu2H)(2)] (coe = cis-cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X-ray crystallography.

机译：报道了反式-[IrCl（NO）（PtBu2H）（2）] BF4（1）的合成和结构表征。在室温下，将原位制备的反式[[IrCl（coe）（PtBu2H）（2）]（coe =顺式环辛烯）与适量的四氟硼酸硝基铵在二氯甲烷中反应，可以高收率制备标题化合物。 1的单晶从二氯甲烷/乙醚中生长，并通过X射线晶体学分析。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2016年第14期|共3页
作者
Boettcher Hans-Christian; Mies Thomas; Mayer Peter;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Nitrosyl complexes; Iridium; Secondary phosphanes; Crystal structure;

机译：亚硝基配合物铱次膦晶体结构;

相似文献

外文文献
中文文献
专利

1. Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)(2)]BF4 [J] . Boettcher Hans-Christian, Mies Thomas, Mayer Peter Zeitschrift fur Anorganische und Allgemeine Chemie . 2016,第14期

机译：反式[IrCl（NO）（PtBu2H）（2）] BF4的合成及分子结构
2. Some reaction chemistry of trans-[Fe(H)(eta(2)-H-2)(eta(2)-dppm)(2)][BF4]. The crystal and molecular structure of trans-[Fe(H)(CH3CN)(eta(2)-dppm)(2)][BF4], dppm = bis(diphenylphosphino)methane [J] . Gao Y., Hughes AN., Spivak GJ., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第22期

机译：反式-[Fe（H）（eta（2）-H-2）（eta（2）-dppm）（2）] [BF4]的一些反应化学。反式-[Fe（H）（CH3CN）（eta（2）-dppm）（2）] [BF4]的晶体和分子结构，dppm =双（二苯基膦基）甲烷
3. PREPARATION, CRYSTAL STRUCTURES, VIBRATIONAL SPECTRA, AND NORMAL COORDINATE ANALYSIS OF THE LINKAGE ISOMERIC CHLORORHODANOIRIDATES(III) TRANS-[IRCL2(SCN)(4)](3-) AND TRANS-[IRCL2(NCS)(SCN)(3)](3-) [German] [J] . Rohde JU., Preetz W. Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第11期

机译：异氰酸氯代异氰酸酯（III）-[IRCL2（SCN）（4）]（3-）和-[IRCL2（NCS）（SCN）（3）]键的制备，晶体结构，振动光谱和正态坐标分析（3-）[德语]
4. Hollow core microstructured optical fibers as support for synthesis of molecularly imprinted polymers [C] . Kirill Y. Presnyakov, Pavel S. Pidenko, Julia S. Skibina, Saratov Meeting: Optical and Nanotechnologies for Biology and Medicine . 2020

机译：中空核心结构光纤作为分子印迹聚合物的合成载体
5. Synthesis and Characterization of Bis(isocyanide)rhenium Complexes as Building Blocks Towards Two- and Three-Dimensional Molecular Structures [D] . Ng, Nicholas Justin. 2018

机译：双（异氰化物）as配合物的合成和表征，作为构建二维和三维分子结构的基础
6. Synthesis and Molecular Structure of Ethyl N-tosyl-(R)-prolyloxy-2(S)-4-cyano-88-ethylenedioxy-5-oxo-5678-tetrahydroindolizin-3-yl Acetate a Key Intermediate in the Total Synthesis of (20S)-Camptothecins [O] . Yun-Yan Kuang, Fen-Er Chen 2007

机译：乙基N-甲苯磺酰基-（R）-脯氨酰氧基 -2（S）-4-氰基-88-乙二氧基-5-氧代-5678-四氢吲哚并-3-乙酸酯（20S）-喜树碱总合成的关键中间体
7. Stereoselective synthesis and reactivity of cis- and trans- dimolybdenum nitrosyl derivatives with the bridging bis(dimethylsilanediyl)di(η5-cyclopentadienyl) ligand. X-ray molecular structures of cis-{Mo(CO)2(NO)}2(μ-(η5-C5H3)2(SiMe2)2}, trans-(Mo(CO)(NO)(CNtBu)}2(μ-(η5-C5H3)2(SiMe2)2}, cis-{Mo2(CO)3(NO)2(PMe3)}{μ-(η5-C 5H3)2(SiMe2)2} and trans-{Mo(NO)(CNtBu)2}2(μ-(η5-C5H3)2(SiMe2)2} [O] . Calvo Pérez Mercedes, Galakhov Mikhail V., Gómez García Roberto, 1997

机译：顺式和反式二钼亚硝酰基衍生物与桥联双（二甲基硅烷二基）二（η5-环戊二烯基）配体的立体选择性合成和反应性。顺式Mo（CO）（NO）（CNtBu）-{Mo（CO）2（NO）} 2（μ-（η5-C5H3）2（SiMe2）2}的X射线分子结构} 2（μ-（η5-C5H3）2（SiMe2）2}，顺式-{Mo2（CO）3（NO）2（PMe3）} {μ-（η5-C5H3）2（SiMe2）2} 和trans-{Mo（NO）（CNtBu）2} 2（μ-（η5-C5H3）2（SiMe2）2}
8. Dinitrogen Difluoride Chemistry. Improved Synthesis of cis- and trans- N2F2, Synthesis and Characterization of N2F+Sn2F9 High-Level Electronic Structure Calculations of cis-N2F2, trans-N2F2, F2N=N, and N2F+, and Mechanism of the trans-cis Isomerization of N2F2 (Preprint) [R] . Christe, K. O., Haiges, R., Wilson, W. W., 2010

机译：二氟化二氮化学。改进的顺式 - 和反式 - N2F2的合成，N2F + sn2F9的合成和表征高级电子结构计算顺式-N2F2，反式N2F2，F2N = N和N2F +，以及N2F2的反式顺式异构化机理（预印本）

Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)(2)]BF4

摘要

著录项

相似文献

相关主题

期刊订阅