Structure determination of a twinned Rb(H2NC10H6SO3) center dot H2O crystal and comparison to related alkali metal aminonaphthalenesulfonates

Martin A.; Pinkerton AA.; Gunderman BJ.; Squattrito PJ.; Parrish D.

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Structure determination of a twinned Rb(H2NC10H6SO3) center dot H2O crystal and comparison to related alkali metal aminonaphthalenesulfonates

机译：孪晶Rb（H2NC10H6SO3）中心点H2O晶体的结构确定及与相关碱金属氨基萘磺酸盐的比较

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Rb(H2NC10H6SO3) . H2O crystallizes in space group P2(1) with two formula units in the asymmetric unit, the crystal being twinned by a 180 degrees rotation about [1 0 0]. The structure was determined from X-ray diffraction data, and refined, based on two twin components, to yield a final R value of 0.0557 for 2754 reflections. The structure consists of alternating layers of aminonaphthalenesulfonate and rubidium ions. There are two distinct rubidium environments, the metal ions linked by the sulfonate groups and bridging water molecules into an infinite sheet. The sulfonate groups are bidentate, monodentate and bridging, all oxygen atoms being bound to at least one metal. The amino groups do not participate in coordination to the metal. Aromatic moieties from neighboring hydrophile metallo-layers interleave to form the hydrophobic layers. There is some similarity to the analogous sodium and potassium structures, however the rubidium compound is distinguished by an infinite cationic layer, rather than columns observed for the other two structures. [References: 5]

机译：Rb（H 2 NC 10 H 6 SO 3）。 H2O在空间组P2（1）中以两个不对称单位的式子结晶，该晶体通过绕[1 0 0]旋转180度而孪晶。根据X射线衍射数据确定结构，并基于两个孪生分量进行精制，以得到2754次反射的最终R值为0.0557。该结构由氨基萘磺酸盐和rub离子的交替层组成。 two环境有两种，一种是通过磺酸盐基团连接的金属离子，另一种是将水分子桥接成无限大的薄片。磺酸根基团是二齿的，单齿的和桥连的，所有的氧原子都与至少一种金属键合。氨基不参与与金属的配位。来自相邻亲水金属层的芳族部分交错形成疏水层。与类似的钠和钾结构有些相似，但是the化合物的特征是无限的阳离子层，而不是其他两种结构的柱。 [参考：5]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2001年第2期|共7页
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Martin A.; Pinkerton AA.; Gunderman BJ.; Squattrito PJ.; Parrish D.;
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1. Structure determination of a twinned Rb(H2NC10H6SO3) center dot H2O crystal and comparison to related alkali metal aminonaphthalenesulfonates [J] . Martin A., Pinkerton AA., Gunderman BJ., Zeitschrift fur Anorganische und Allgemeine Chemie . 2001,第2期

机译：孪晶Rb（H2NC10H6SO3）中心点H2O晶体的结构确定及与相关碱金属氨基萘磺酸盐的比较
2. Role of the alkali metal ion and hydrogen bonds in M[VO(O-2)(2)bpy] center dot nH(2)O (M = Li+, Na+, K+ and Rb+) and Cs[VO(O-2)(2)bpy] center dot H2O2 complexes: The X-ray crystal structures and spectroscopic properties [J] . Przybylski W, Grybos R, Rehder D, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2009,第8期

机译：碱金属离子和氢键在M [VO（O-2）（2）bpy]中心点nH（2）O（M = Li +，Na +，K +和Rb +）和Cs [VO（O-2）（2）[bpy]中心点过氧化氢配合物：X射线晶体结构和光谱性质
3. About alkali metal dicyanamides: syntheses, single-crystal structure determination, DSC/TG and vibrational spectra of KCs[N(CN)(2)](2) and NaRb2[N(CN)(2)](3) center dot H2O [J] . Reckeweg Olaf, Wakabayashi Ryo H., DiSalvo Francis J., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2015,第6期

机译：关于碱金属双氰胺：KCs [N（CN）（2）]（2）和NaRb2 [N（CN）（2）]（3）中心点H2O的合成，单晶结构确定，DSC / TG和振动光谱
4. Syntheses and Crystal Structures of Two Octacyanometalate Networks:Ni(L1)3W(CN)82·4H2O and Ni(L2)2Mo(CN)8·8H2O [C] . International symposium on fine chemistry and functional polymers . 2008

机译：两个八环素网络网络的合成和晶体结构：Ni（L1） 3 W（CN）8 2·4H2O和Ni（L2） 2 Mo（CN）8·8H2O
5. First principles exploration of crystal structures and physical properties of silicon hydrides KSiH3 and K2SiH6, alkali and alkaline earth metal carbides, and II-V semiconductors ZnSb and ZnAs. [D] . Benson, Daryn Eugene. 2013

机译：首先，探讨氢化硅KSiH3和K2SiH6，碱金属和碱土金属碳化物以及II-V半导体ZnSb和ZnAs的晶体结构和物理性质的原理。
6. Icosahedral and decagonal quasicrystals of intermetallic compounds are multiple twins of cubic or orthorhombic crystals composed of very large atomic complexes with icosahedral point-group symmetry in cubic close packing or body-centered packing: Structure of decagonal Al6Pd [O] . Linus Pauling 1989

机译：金属间化合物的二十面体和十面体准晶体是立方或正交晶体的多个孪晶由立方密堆积或体心堆积中具有二十面体点群对称的非常大的原子络合物组成：十方Al6Pd结构
7. Crystal structure of 6-acetyl-3,4-dimethy1-5-[(2-oxo-1,3-oxazolidin-3-yl)-carbonyl]tetrahydropyridin-2(1H)-one-water (4/1), C13H18N2O5 center dot 0.25 H2O [O] . Tinant, Bernard, Declercq, Jean-Paul, Jnoff, Eric, 1999

机译：6-乙酰基-3,4-二甲基1-5-[（2-氧代-1,3-恶唑烷-3-基）-羰基]四氢吡啶-2-2（1H）-单水（4/1）的晶体结构， C13H18N2O5中心点0.25 H2O

Structure determination of a twinned Rb(H2NC10H6SO3) center dot H2O crystal and comparison to related alkali metal aminonaphthalenesulfonates

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