1,2-BIS(DIMETHYLAMINO)-3,4,5-TRIPHENYL-3,4,5-TRIPHOSPHA-1,2-DIBOROLANE AND 1,2-BIS(DIMETHYLAMINO)-3,4,5,6-TEBRA-TBUTYL-3,4,5,6-TETRAPHOSPHA-1,2-DIBOR INE - SYNTHESIS AND STRUCTURE AS WELL AS CALCULATIONS ON THE MOLECULAR STRUCTURE [German]

Riegel B.; Schwarz W.; Heckmann G.; Binder H.; Fluck E. Dransfeld A.; Schleyer PV.; Hausen HD.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >1,2-BIS(DIMETHYLAMINO)-3,4,5-TRIPHENYL-3,4,5-TRIPHOSPHA-1,2-DIBOROLANE AND 1,2-BIS(DIMETHYLAMINO)-3,4,5,6-TEBRA-TBUTYL-3,4,5,6-TETRAPHOSPHA-1,2-DIBOR INE - SYNTHESIS AND STRUCTURE AS WELL AS CALCULATIONS ON THE MOLECULAR STRUCTURE [German]

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1,2-BIS(DIMETHYLAMINO)-3,4,5-TRIPHENYL-3,4,5-TRIPHOSPHA-1,2-DIBOROLANE AND 1,2-BIS(DIMETHYLAMINO)-3,4,5,6-TEBRA-TBUTYL-3,4,5,6-TETRAPHOSPHA-1,2-DIBOR INE - SYNTHESIS AND STRUCTURE AS WELL AS CALCULATIONS ON THE MOLECULAR STRUCTURE [German]

机译：1,2-双（二甲氨基）-3,4,5-三苯-3,4,5-三磷-1,2-二硼烷和1,2-双（二甲氨基）-3,4,5,6-TEBRA- TBUTYL-3,4,5,6-四氟-1,2-二硼烷-的合成与结构以及分子结构的计算[德语]

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The diphosphides K-2[(C6H5)P-(C6H5)P-P(C6H5)], 4 or K-2[(tBuP)-(tBuP)(2)-P(tBu)], 5, react with (ClBNMe(2))(2) to form the binary 5-membered ring system 1,2-bis(dimethylamino)-3,4, 5-triphenyl-3,4,5-triphospha-1,2-diborolane (C6H5P)(3)(BNMe(2))(2), 2a, and the 6-membered ring system 1,2-bis(dimethylamino)-3,4,5,6-tetra-tbutyl-3,4,5,6-tetraphospha-1,2-dibor ine, (tBuP)(4)(BNMe(2))(2), 3a, respectively. 2a and 3a could be obtained in a pure form and characterized NMR spectroscopically and by X-ray structure analyses. The two ring systems are folded; 2a exists in the ''envelope''- 3a in the ''boat''-conformation. Ab initio computations for 3,4,5-triphospha-1,2-diborolane M5 show that the global minimum is characterized by one E-P double bond. The parent compound geometry M6 is characterized by transannular bonding in the PH-BH-BH-PH moiety which differs in character from those in the four- and five-membered rings (BH)(2)(PH)(2) and (BH)(2)(PH)(3) M5 d, respectively. Explicit calculation of the influence of amino substituents on boron improved agreement of the bond length between computed and X-ray data. [References: 25]

机译：二磷化物K-2 [（（C6H5）P-（C6H5）PP（C6H5）]，4或K-2 [（tBuP）-（tBuP）（2）-P（tBu）]，5，与（ClBNMe（ 2））（2）形成二元5元环系统1,2-双（二甲基氨基）-3,4，5-三苯基-3,4,5-三磷-1,2-二硼烷（C6H5P）（3 ）（BNMe（2））（2），2a和6元环系统1,2-双（二甲基氨基）-3,4,5,6-四叔丁基-3,4,5,6-四磷-1,2-diborine，（tBuP）（4）（BNMe（2））（2），3a。可以以纯净形式获得图2a和3a，并通过X射线结构分析在光谱上表征了NMR。两个环系统已折叠; 2a存在于“船”形的“信封”中-3a。 3,4,5-三磷-1,2-二硼烷M5的从头算计算表明，整体最小值由一个E-P双键表征。母体化合物M6的特征在于PH-BH-BH-PH部分中的跨环键，其特征不同于四元和五元环（BH）（2）（PH）（2）和（BH ）（2）（PH）（3）M5 d。氨基取代基对硼的影响的显式计算提高了计算和X射线数据之间键长的一致性。 [参考：25]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1996年第9期|共9页
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Riegel B.; Schwarz W.; Heckmann G.; Binder H.; Fluck E. Dransfeld A.; Schleyer PV.; Hausen HD.;
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中图分类化学;
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1; 2-bis(dimethylamino)-3; 4; 5-triphenyl-3; 4; 5-triphospha-1; 2-diborolane; 1; 2-bis(dimethylamino)-3; 4; 5; 6-tetra-tbutyl-3; 4; 5; 6-tetraphospha-1; 2-dibor ine; Preparation; Nmr; Molecular structures; Ab initio calculations; Chemistry; Phosphorus;

机译：1;2-双（二甲基氨基）-3;4;5-三苯基-3;4;5-三磷-1;2-二硼烷;1;2-双（二甲基氨基）-3;4;5;6-四-叔丁基-3;4;5;6-tetraphospha-1;2-diborine;制备;Nmr;分子结构;Ab从头算;化学;磷;

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1. 1,2-BIS(DIMETHYLAMINO)-3,4,5-TRIPHENYL-3,4,5-TRIPHOSPHA-1,2-DIBOROLANE AND 1,2-BIS(DIMETHYLAMINO)-3,4,5,6-TEBRA-TBUTYL-3,4,5,6-TETRAPHOSPHA-1,2-DIBOR INE - SYNTHESIS AND STRUCTURE AS WELL AS CALCULATIONS ON THE MOLECULAR STRUCTURE [German] [J] . Riegel B., Schwarz W., Heckmann G., Zeitschrift fur Anorganische und Allgemeine Chemie . 1996,第9期

机译：1,2-双（二甲氨基）-3,4,5-三苯-3,4,5-三磷-1,2-二硼烷和1,2-双（二甲氨基）-3,4,5,6-TEBRA- TBUTYL-3,4,5,6-四氟-1,2-二硼烷-的合成与结构以及分子结构的计算[德语]
2. Synthesis of the diphenylacetylene-based, tetra-amine ligand 1,2-bis(3,5-bis[(dimethylamino)methyl]phenyl)acetylene by palladium-catalysed cross-coupling: isolation and crystal structure of the catalyst trans-(3,5-bis[(dimethylamino)methyl]-phenyl)bi [J] . Spee MPR., Steenwinkel P., Kooijman H., Journal of Organometallic Chemistry . 2000,第1期

机译：钯催化交叉偶联合成二苯乙炔基四胺配体1,2-双（3,5-双[（二甲基氨基）甲基]苯基）乙炔：催化剂反式-（3的分离和晶体结构，5-双[（二甲氨基）甲基]-苯基）bi
3. ROTATIONAL ISOMERISM IN 1,2-DIAMINOETHANE, 1,2-BIS(DIMETHYLAMINO)ETHANE AND 1,2-BIS(DIETHYLAMINO)ETHANE [J] . Lam YL., Huang HH. Journal of Molecular Structure . 1997,第1a2期

机译：1,2-二氨基乙烷，1,2-双（二甲基氨基）乙烷和1,2-双（二乙基氨基）乙烷的旋转异构
4. Synthesis and Characterization of Transition Metal Complexes of 1,2-Bis(3,5-dimethylpyrazol-1 -yl)-1,2-ethanediol [C] . Galyna A. Anosova, Vladislava V. Matveevskaya, Nurgul A. Pirmanova International Conference for Young Scientists "High Technology: Research and Applications" . 2016

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5. Transition-metal-catalyzed enantioselective synthesis and functionalization of 1,2- and 1,4-bis(boronate)esters. [D] . Burks, Heather Elizabeth. 2008

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7. CCDC 1024868: Experimental Crystal Structure Determination : tris(mu-3,4,5,6-tetrafluorobenzene-1,2-diyl)-tri-mercury bisthieno[3,2-b:2',3'-d]thiophene 1,2-dichloroethane solvate [O] . Castañeda, Raúl, Khrustalev, Victor N., Fonari, Alexandr, 2015

机译：CCDC 1024868：实验晶体结构测定：三（mu-3,4,5,6-四氟苯-1,2-二基）-三汞联苯并[3,2-b：2'，3'-d]噻吩1 ，2-二氯乙烷溶剂化物
8. Summary of Health Effects Alleged by a Property Owner Following Potential Inhalation Exposure to a Chemical Mixture Manufactured or Processed by the Company with 2-Propanol, 1-(bis(3-(dimethylamino) propyl)amino); 1,3-Propanediamine, N1-(3-(dimethylamino)propyl)-N1, N3, N3-trimethyl; 1H-Imidazole, 1,2-dimethyl; 1,2-Dichloroethylene; 1,1,1,3,3-Pentafluoropropane; 2-Butoxyethanol. [R] . 2013

机译：在公司制造或加工的化学混合物中，使用2-丙醇，1-（双（3-（二甲基氨基）丙基）氨基）吸收潜在吸入后财产所有者所指称的健康影响摘要; 1,3-丙二胺，N1-（3-（二甲基氨基）丙基）-N1，N3，N3-三甲基; 1H-咪唑，1,2-二甲基; 1,2-二氯乙烯; 1,1,1,3,3-五氟丙烷; 2-丁氧基乙醇。

1,2-BIS(DIMETHYLAMINO)-3,4,5-TRIPHENYL-3,4,5-TRIPHOSPHA-1,2-DIBOROLANE AND 1,2-BIS(DIMETHYLAMINO)-3,4,5,6-TEBRA-TBUTYL-3,4,5,6-TETRAPHOSPHA-1,2-DIBOR INE - SYNTHESIS AND STRUCTURE AS WELL AS CALCULATIONS ON THE MOLECULAR STRUCTURE [German]

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