Two-Dimensional Divalent Metal Coordination Polymers Containing 3,4 '-Dipyridylketone Tethers: Layer Topology Tuning by Anion Binding Preferences

Farnum GA; Montney MR; Supkowski RM; LaDuca RL

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Two-Dimensional Divalent Metal Coordination Polymers Containing 3,4 '-Dipyridylketone Tethers: Layer Topology Tuning by Anion Binding Preferences

【24h】

Two-Dimensional Divalent Metal Coordination Polymers Containing 3,4 '-Dipyridylketone Tethers: Layer Topology Tuning by Anion Binding Preferences

机译：包含3,4'-二吡啶基酮系链的二维二价金属配位聚合物：通过阴离子键合偏好进行层拓扑调整

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Slow diffusion of aqueous cobalt thiocyanate or cadmium perchlorate and ethanolic solutions of 3,4'-dipyridylketone (3,4'-dpk) generated the coordination polymers {[Co(NCS)(2)(3,4'-dpk)(2)]center dot 2H(2)O}(n) (1) and {[Cd(H2O)(2)(3,4'-dpk)(2)](ClO4)(2)center dot 2H(2)O}(n) (2), which were structurally characterized by single-crystal X-ray diffraction. The structure of I consists of interdigitated neutral [Co(NCS)(2)(3,4'-dpk)(2)](n) (4,4) rectangular grid coordination polymer layers. However, compound 2 manifests cationic [Cd(H2O)(2)(3,4'-dpk)(2)](n)(2n+) two-dimensional (6,3) herringbone lattices connected through hydrogen bonding mediated by interlamellar unligated perchlorate anions. Upon excitation with ultraviolet radiation, 2 emits blue-violet light, ascribed to pi-pi* transitions within the pyridyl rings of the 3,4'-dpk ligands. Thermal decomposition behavior of 1 is also discussed.

机译：硫氰酸钴或高氯酸镉水溶液的缓慢扩散以及3,4'-联吡啶酮（3,4'-dpk）的乙醇溶液生成配位聚合物{[Co（NCS）（2）（3,4'-dpk）（2 ）]中心点2H（2）O}（n）（1）和{[Cd（H2O）（2）（3,4'-dpk）（2）]（ClO4）（2）中心点2H（2） O}（n）（2），其结构通过单晶X射线衍射表征。 I的结构由相互交叉的中性[Co（NCS）（2）（3,4'-dpk）（2）]（n）（4,4）矩形网格配位聚合物层组成。但是，化合物2表现出阳离子[Cd（H2O）（2）（3,4'-dpk）（2）]（n）（2n +）二维（6,3）人字形晶格，其通过未键合的层间介导的氢键连接高氯酸根阴离子。在紫外线激发下，2发出蓝紫色光，这归因于3,4'-dpk配体的吡啶环内的pi-pi *跃迁。还讨论了1的热分解行为。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第11期|共6页
作者
Farnum GA; Montney MR; Supkowski RM; LaDuca RL;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Hydrothermal synthesis; Cobalt; Cadmium; Isothiocyanate; Perchlorate; Luminescence;

机译：水热合成钴镉异硫氰酸盐高氯酸盐发光;

相似文献

外文文献
中文文献
专利

1. Two-Dimensional Divalent Metal Coordination Polymers Containing 3,4 '-Dipyridylketone Tethers: Layer Topology Tuning by Anion Binding Preferences [J] . Farnum GA, Montney MR, Supkowski RM, Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第11期

机译：包含3,4'-二吡啶基酮系链的二维二价金属配位聚合物：通过阴离子键合偏好进行层拓扑调整
2. Divalent metal 1,3-phenylenediacetate coordination polymers with rigid or flexible dipyridyl tethers: Chains, layers, and interpenetrated networks [J] . Blake K.M., Johnston L.L., Braverman M.A., Inorganica Chimica Acta . 2010,第10期

机译：具有刚性或柔性二吡啶基系链的二价金属1,3-苯二乙酸酯配位聚合物：链，层和互穿网络
3. Tether length control of topology in cadmium 4-methylphthalate two-dimensional coordination polymers: An acentric buckled grid and a rare self-catenated layer [J] . Farnum G.A., Pochodylo A.L., Laduca R.L. Crystal growth & design . 2011,第3期

机译：4-甲基邻苯二甲酸镉二维配位聚合物拓扑结构的系链长度控制：无心屈曲网格和稀有的自连接层
4. (Invited) Effect of Water Management for Cathode Catalyst Layers Using a Non-Noble Metal Catalyst and a Novel Polymer Electrolyte on Cell Performance Hysteresis in Anion Exchange Membrane Fuel Cells [C] . Makoto Uchida, Kanji Otsuji, Naoki Yokota, Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：（邀请）阴极催化剂层的水管理使用非贵金属催化剂和新型聚合物电解质在阴离子交换膜燃料电池中的细胞性能滞后的影响
5. Tetradipicolyamine-substituted resorc[4]arene cavitands: I. Anion binding and transition metal assembled coordination cages and nanoarchitectures. II. Polymer inclusion membranes applied to anion separations. [D] . Gardner, Joseph S. 2005

机译：Tetradipicolyamine取代的间苯二酚[4]芳烃空洞：I.阴离子结合和过渡金属组装的配位笼和纳米结构。二。适用于阴离子分离的聚合物包合物膜。
6. Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures [O] . David K. Geiger, Dylan E. Parsons, Bracco A. Pagano 2016

机译：两种具有桥联乙酸盐和苯二二胺配体的镉配位聚合物具有二维层状结构
7. Crystal structures of a family of layered coordination polymers containing divalent metal ions (Mn2+, Co2+, Ni2+ and Zn2+) and the 3-amino 4-methyl benzoate ion [O] . Khosa, M. K., Wood, P. T., Humphrey, S. M., 2015

机译：包含二价金属离子（Mn2 +，Co2 +，Ni2 +和Zn2 +）和3-氨基4-甲基苯甲酸酯离子的分层配位聚合物系列的晶体结构

Two-Dimensional Divalent Metal Coordination Polymers Containing 3,4 '-Dipyridylketone Tethers: Layer Topology Tuning by Anion Binding Preferences

摘要

著录项

相似文献

相关主题

期刊订阅