The inverse perovskite (Ca_2EuN_x)Sn: A rare example for a homogeneously mixed-valent compound?

G?bler F.; Br?unling D.; Schnelle W.; Schellenberg I.; P?ttgen R.; Niewa R.

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The inverse perovskite (Ca_2EuN_x)Sn: A rare example for a homogeneously mixed-valent compound?

机译：反钙钛矿（Ca_2EuN_x）Sn：均匀混合价化合物的稀有例子吗？

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The cubic Perovskite (Ca_2EuN_(0.75))Sn was synthesized in a solid state reaction from EuN, Ca, and Sn. Nitrogen deficiency and Ca/Eu disorder is in agreement with results from chemical analysis, X-ray diffraction, and M?ssbauer spectroscopy. Magnetic susceptibility measurements as well as M?ssbauer and X-ray absorption spectroscopy indicate a mixed-valent situation with di- and trivalent europium, apparently situated together with calcium on one crystallographic site. According to electrical resistivity measurements the title compound represents a heavily doped semiconductor.

机译：在固相反应中由EuN，Ca和Sn合成了立方钙钛矿（Ca_2EuN_（0.75））Sn。氮缺乏和Ca / Eu紊乱与化学分析，X射线衍射和Msssbauer光谱的结果一致。磁化率测量以及Mssbauer和X射线吸收光谱表明，二价和三价euro呈混合价态，显然与钙一起位于一个晶体学位置。根据电阻率测量，标题化合物表示重掺杂半导体。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2011年第7期|共6页
作者
G?bler F.; Br?unling D.; Schnelle W.; Schellenberg I.; P?ttgen R.; Niewa R.;
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正文语种 eng
中图分类化学;
关键词
Inverse Perovskite; Mixed-valent europium; M?ssbauer spectroscopy; Nitrides; X-ray absorption spectroscopy;

机译：逆钙钛矿;混合M;Msssbauer光谱;氮化物;X射线吸收光谱;

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1. The inverse perovskite (Ca_2EuN_x)Sn: A rare example for a homogeneously mixed-valent compound? [J] . G?bler F., Br?unling D., Schnelle W., Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第7期

机译：反钙钛矿（Ca_2EuN_x）Sn：均匀混合价化合物的稀有例子吗？
2. Ag_3(SO_3F)_4: A rare example of a mixed-valent Ag~(II)/Ag~I compound showing 1D antiferromagnetism [J] . Micha?owski T., Malinowski P.J., Derzsi M., European journal of inorganic chemistry . 2011,第16期

机译：Ag_3（SO_3F）_4：具有一维反铁磁性的混合价Ag〜（II）/ Ag〜I化合物的罕见示例
3. New structures formed by R_3Au_4Sn_3, R_5Au_8Sn_5 and R_3Au_6Sn_5 compounds (R = rare earths) [J] . M.L. Fornasini, D. Mazzone, A. Provino Intermetallics . 2014,第Null期

机译：由R_3Au_4Sn_3，R_5Au_8Sn_5和R_3Au_6Sn_5化合物形成的新结构（R =稀土）
4. Rare Mixed-valent Rare Earth Metal Complexes [C] . Glen B. Deacon, Peter C. Junk, Jun Wang Rare Earth Research Conference . 2019

机译：罕见的混合价稀土金属配合物
5. Synthesizing new [(SnSe)1.15]m(TSe2)n, [(SnSe)1.16]m(VSe2)n[(SnSe)1.16]p(TaSe2)q, and (SnSe)1.16(V.51Ta.49Se2) intergrowth compounds (T = V and Ta). [D] . Atkins, Ryan Elliot. 2013

机译：合成新的[（SnSe）1.15] m（TSe2）n，[（SnSe）1.16] m（VSe2）n [（SnSe）1.16] p（TaSe2）q和（SnSe）1.16（V.51Ta.49Se2）共生化合物（T = V和Ta）。
6. Sn(IV)-free tin perovskite films realized by in situ Sn(0) nanoparticle treatment of the precursor solution [O] . Tomoya Nakamura, Shinya Yakumaru, Minh Anh Truong, -1

机译：通过前驱体溶液的原位Sn（0）纳米粒子处理实现的无Sn（IV）钙钛矿薄膜
7. Single crystals of mixed Br/Cl and Sn-doped formamidinium lead halide perovskites via inverse temperature crystallization [O] . Michael Ng, Jonathan E. Halpert 2020

机译：混合Br / Cl和Sn掺杂甲脒铅卤化物钙钙酸盐通过逆温度结晶
8. Structural distortion in RPt2Sn2 compounds (R = rare earth). [R] . M. Latroche M. Selsane C. Godart G. Schiffmacher W. P. Beyerman 1991

机译：Rpt2sn2化合物（R =稀土）的结构变形。

The inverse perovskite (Ca_2EuN_x)Sn: A rare example for a homogeneously mixed-valent compound?

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