Synthesis, crystal structure, and physical properties of a barium(II) benzene-1, 2, 3-tricarboxylic acid complex

Wu G.; Feng J.-H.; Wang X.-F.

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Synthesis, crystal structure, and physical properties of a barium(II) benzene-1, 2, 3-tricarboxylic acid complex

机译：钡（II）苯-1，2，3-三羧酸配合物的合成，晶体结构和物理性质

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A coordination polymer [Ba _(12)(btc) _8(H _2O) _(23)] (1) was obtained by self-assembly of the corresponding metal carbonate with benzene-1, 2, 3-tricarboxylic acid ligand (H _3btc), and its structure was determined by single-crystal X-ray diffraction studies. The results revealed that complex 1 has a three dimensional structure. In 1, the btc ~(3-) anions adopt four different conformation and coordination modes. Bridging btc ~(3-) anions and μ _2-bridging water molecules connect Ba ~(II) ions to generate a two dimensional layer. Further, μ _2-bridging coordinated water molecules connect the Ba ~(II) ions of neighboring layers to form a three dimensional structure. Additionally, the luminescent property and thermal stability of 1 were investigated.

机译：通过将相应的金属碳酸盐与苯-1、2、3-三羧酸配体（H）自组装获得配位聚合物[Ba _（12）（btc）_8（H _2O）_（23）]（1） _3btc），并通过单晶X射线衍射研究确定其结构。结果表明，复合物1具有三维结构。在1中，btc〜（3-）阴离子采用四种不同的构象和配位模式。桥接btc〜（3-）阴离子和μ_2桥接水分子连接Ba〜（II）离子以生成二维层。此外，μ_2桥联的配位水分子连接相邻层的Ba〜（II）离子以形成三维结构。另外，研究了1的发光性质和热稳定性。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第6期|共6页
作者
Wu G.; Feng J.-H.; Wang X.-F.;
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正文语种 eng
中图分类化学;
关键词
Barium; Carboxylic acids; Crystal structure; Luminescence; Thermal stability;

机译：钡;羧酸;晶体结构;发光;热稳定性;

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1. Synthesis, crystal structure, and physical properties of a barium(II) benzene-1, 2, 3-tricarboxylic acid complex [J] . Wu G., Feng J.-H., Wang X.-F. Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第6期

机译：钡（II）苯-1，2，3-三羧酸配合物的合成，晶体结构和物理性质
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Synthesis, crystal structure, and physical properties of a barium(II) benzene-1, 2, 3-tricarboxylic acid complex

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