Synthesis, crystal structure, and properties of a cadmium(II) complex with the flexible ligand (1'H-[2, 2']Biimidazoly-1-yl)-acetic Acid

Wang J.; Tao J.-Q.; Xu X.-J.; Tan C.-Y.

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Synthesis, crystal structure, and properties of a cadmium(II) complex with the flexible ligand (1'H-[2, 2']Biimidazoly-1-yl)-acetic Acid

机译：带有柔性配体（1'H- [2,2']二咪唑基-1-基）-乙酸的镉（II）配合物的合成，晶体结构和性质

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A novel coordination polymer {[Cd(BDAC)] _2·H _2O} _n (1) [HBDAC = (1'H-[2, 2']biimidazoly-1-yl)-acetic acid] was synthesized under hydrothermal conditions and characterized by elemental analysis and single-crystal X-ray diffraction. Complex 1 crystallizes in the acentric orthorhombic space group Ccc2. The Cd1 atoms and BDAC ~(2-) ligands construct [Cd1(BDAC)] rhomboid grid (4, 4)-topology layer motifs, whereas the Cd2 atoms and BDAC ~(2-) ligands form [Cd2(BDAC)] 1D coordination polymer ribbons. Furthermore, adjacent lay motifs are linked into 3D net structures by 1D coordination polymer ribbons with 4-connected 3D trinodal {4 ~28 ~210 ~2}{4 ~46 ~2}{4 ~36 ~28} _2 topology. The measurement of electric hysteresis loops indicated that complex 1 displays a ferroelectric characteristic.

机译：在水热条件下合成了新型配位聚合物{[Cd（BDAC）] _2·H _2O} _n（1）[HBDAC =（1'H- [2，2'] biimidazolyly-1-yl）-acetic acid]，通过元素分析和X射线单晶衍射进行表征。配合物1在非对称正交晶体空间群Ccc2中结晶。 Cd1原子和BDAC〜（2-）配体构成[Cd1（BDAC）]菱形网格（4，4）-拓扑层图案，而Cd2原子和BDAC〜（2-）配体形成[Cd2（BDAC）] 1D配位聚合物色带。此外，相邻的躺位图案通过具有4个连接的3D三节点{4〜28〜210〜2} {4〜46〜2} {4〜36〜28} _2拓扑的1D配位聚合物带连接到3D网络结构中。电滞回线的测量表明，配合物1显示出铁电特性。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第9期|共4页
作者
Wang J.; Tao J.-Q.; Xu X.-J.; Tan C.-Y.;
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正文语种 eng
中图分类化学;
关键词
Cadmium; Crystal structure; Ferroelectric property; Polar solid-state materials; Thermal stability;

机译：镉;晶体结构;铁电性能;极性固态材料;热稳定性;

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1. Synthesis, crystal structure, and properties of a cadmium(II) complex with the flexible ligand (1'H-[2, 2']Biimidazoly-1-yl)-acetic Acid [J] . Wang J., Tao J.-Q., Xu X.-J., Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第9期

机译：带有柔性配体（1'H- [2,2']二咪唑基-1-基）-乙酸的镉（II）配合物的合成，晶体结构和性质
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Synthesis, crystal structure, and properties of a cadmium(II) complex with the flexible ligand (1'H-[2, 2']Biimidazoly-1-yl)-acetic Acid

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