Chemical Sodiation of V2O5 by Na2S

Haberkorn Robert; Bauer Jessica; Kickelbick Guido

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Chemical Sodiation of V2O5 by Na2S

机译：Na2S对V2O5的化学合成

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Chemical sodiation of V2O5 at low temperatures allows to synthesize NaxV2O5 with 0 <= x <= 1, while classic high temperature syntheses yield in either x <= 0.02 (alpha-phase) or 0.7 <= x (alpha'-phase), or other phases (beta-phase, delta-phase) or mixtures thereof. A suspension of V2O5 in acetonitrile and Na2S as sodiation agent were used. The maximum amount of sodiation was obtained by using an excess of Na2S, refluxing the acetonitrile during the reaction, and precedent ball milling of the V2O5. If only low amounts of Na2S were used as starting material, a mixture of fractions of NaxV2O5 with different values of x was obtained. All these fractions belong to the alpha- or alpha'-phase, space group Pmmn.

机译：在低温下化学合成V2O5可以合成0 <= x <= 1的NaxV2O5，而经典的高温合成则以x <= 0.02（α相）或0.7 <= x（α'相）或其他相（β相，δ相）或其混合物。使用V2O5在乙腈中的悬浮液和Na2S作为助成剂。通过使用过量的Na2S，在反应过程中使乙腈回流以及先进行V2O5球磨来获得最大量的硝化作用。如果仅使用少量的Na2S作为起始原料，则将获得具有不同x值的NaxV2O5馏分的混合物。所有这些分数都属于α相或α'相空间群Pmmn。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2014年第15期|共6页
作者
Haberkorn Robert; Bauer Jessica; Kickelbick Guido;
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正文语种 eng
中图分类化学;
关键词
X-ray diffraction; Rietveld analysis; Sodiation; Cathode material; Vanadium;

机译：X射线衍射;Rietveld分析;碱化;阴极材料;钒;

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1. Chemical Sodiation of V2O5 by Na2S [J] . Haberkorn Robert, Bauer Jessica, Kickelbick Guido Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第15期

机译：Na2S对V2O5的化学合成
2. Recycling wood pulping chemicals by molten salt electrolysis: cyclic voltammetry of mixtures containing Na2CO3 and Na2SO4 [J] . R. Wartena, J. Winnick, P.H. Pfromm Journal of Applied Electrochemistry . 2002,第4期

机译：熔融盐电解回收木浆化学品：循环伏安法测定Na2 CO3 和Na2 SO4 的混合物
3. Sodiation‐Desodiation Cycling: Surface‐Coating‐Mediated Electrochemical Performance in CuO Nanowires during the Sodiation–Desodiation Cycling (Adv. Mater. Interfaces 4/2018) [J] . Liu Huihui, Zheng He, Li Lei, Advanced materials interfaces . 2018,第4期

机译：SODIAT-DESODIATIACING：CUO纳米线中的表面涂层介导的电化学性能在加密 - 退出循环期间（ADV。母体。界面4/2018）
4. First-Principles Study of the Electrochemical Sodiation of Rutile-Type Vanadium Dioxide [C] . Daniel Koch, Sergei Manzhos 日本化学会春季年会 . 2020

机译：金红石型二氧化钒电化学加密的第一原理研究
5. Mixed Glass Former Effect of 0.5 Na2S + 0.5[xSiS 2 + (1--x) PS5/2] and 0.67 Na2S + 0.33[xSiS 2 + (1--x) PS5/2] Glass Systems [D] . Watson, Deborah Elizabeth. 2017

机译：0.5 Na2S + 0.5 [xSiS 2 +（1–x）PS5 / 2]和0.67 Na2S + 0.33 [xSiS 2 +（1–x）PS5 / 2]玻璃系统的混合玻璃前效应
6. Electrochemical Sodiation/Desodiation into Mn [O] . Nor Fazila Mahamad Yusoff, Nurul Hayati Idris, *, 2020

机译：将电化学加密/退出到Mn
7. Sodiation-Desodiation Cycling: Surface-Coating-Mediated Electrochemical Performance in CuO Nanowires during the Sodiation-Desodiation Cycling (Adv. Mater. Interfaces 4/2018) [O] . Huihui Liu, He Zheng, Lei Li, 2018

机译：调解撤分循环：CuO纳米线中CuO纳米线中的表面涂层介导的电化学性能（ADV。母体。界面4/2018）
8. In-Situ, Real-Time Monitoring of Mechanical and Chemical Structure Change in a V2O5 Battery Electrode Using a MEMS Optical Sensor. [R] . Jung, H., Gnerlich, M., Talin, A., 2014

机译：使用mEms光学传感器实时监测V2O5电池电极中的机械和化学结构变化。

Chemical Sodiation of V2O5 by Na2S

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