The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me_2AsS_2)_2Ga]_2S·0.75H_2O: A Hydrolysis Product of (Me_2AsS_2)_3Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands

Constantina Papatriantafyllopoulou; Vassilios Nastopoulos; Panayiotis V. Ioannou

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The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me_2AsS_2)_2Ga]_2S·0.75H_2O: A Hydrolysis Product of (Me_2AsS_2)_3Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands

机译：硫化双（二甲基二硫代砷化镓）镓[（Me_2AsS_2）_2Ga] _2S·0.75H_2O的结构：（Me_2AsS_2）_3Ga的水解产物，其中包含桥联硫化物以及侧链和桥联二甲基二硫代砷化镓配体。

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The complex (Me_2AsS_2)_3Ga (1) attracted water molecules that slowly and completely hydrolyzed it. The product was the dinuclear gallium compound (Me_2AsS_2)_2Ga–S–Ga(S_2AsMe_2)_2 (2) as 2·0.75H_2O, which was structurally characterized with X-ray crystallography (P2_12_12_1, R_1 = 0.0321, wR_2 = 0.0622). Compound 2 shows an approximate non-crystallographic twofold axis. The packing in the crystalline state is dictated by the mediation of crystallization water molecules, which connect the complex units through strong O–H···S and weak C–H···O hydrogen bonds into infinite zigzag chains.

机译：配合物（Me_2AsS_2）_3Ga（1）吸引了水分子，使它缓慢而完全地水解。产物为双核镓化合物（Me_2AsS_2）_2Ga–S–Ga（S_2AsMe_2）_2（2）为2·0.75H_2O，其结构经X射线晶体学表征（P2_12_12_1，R_1 = 0.0321，wR_2 = 0.0622）。化合物2显示出近似的非晶体学双轴。结晶状态下的堆积是由结晶水分子介导的，结晶水分子通过强O-H··S和弱CH···O氢键将复杂的单元连接成无限的之字形链。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2014年第9期|共4页
作者
Constantina Papatriantafyllopoulou; Vassilios Nastopoulos; Panayiotis V. Ioannou;
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正文语种 eng
中图分类化学;
关键词
Dimethyldithioarsinato ligand; Gallium; X-ray crystallography;

机译：二甲基二硫代s配体;镓;X射线晶体学;

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1. The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me_2AsS_2)_2Ga]_2S·0.75H_2O: A Hydrolysis Product of (Me_2AsS_2)_3Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands [J] . Constantina Papatriantafyllopoulou, Vassilios Nastopoulos, Panayiotis V. Ioannou Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第8a9期

机译：硫化双（二甲基二硫代砷化镓）镓[（Me_2AsS_2）_2Ga] _2S·0.75H_2O的结构：（Me_2AsS_2）_3Ga的水解产物，其中包含桥联硫化物以及侧链和桥联二甲基二硫代砷化镓配体。
2. Zero-Dimensional Units of Ligand-Bridged Gallium-Sulfide Supertetrahedra [J] . Vaqueiro P, Romero ML Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第3期

机译：配体桥式硫化镓超四面体的零维单位
3. Zero-Dimensional Units of Ligand-Bridged Gallium-Sulfide Supertetrahedra [J] . Vaqueiro P, Romero ML Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第3期

机译：配体桥式硫化镓超四面体的零维单位
4. Synthesis and crystal structures of (fulvalene)W2(SH)2(CO)6, (fulvalene)W2(mu-S2)(CO)6, and (fulvalene)W2(mu-S)(CO)6-low valent tungsten carbonyl sulfide and disulfide complexes stabilized by the bridging fulvalene ligand [O] . Capps, Kenneth B., Bauer, Andreas, Abboud, Khalil, 2002

机译：（富勒烯）W2（sH）2（CO）6，（富勒烯）W2（mu-s2）（CO）6和（富勒烯）W2（mu-s）（CO）6-低价钨的合成和晶体结构通过桥连富勒烯配体稳定的硫化羰和二硫化物配合物

The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me_2AsS_2)_2Ga]_2S·0.75H_2O: A Hydrolysis Product of (Me_2AsS_2)_3Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands

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