Between Oxoborate and Nitridoborate:The Oxonitridoborate Oxide La_3(OBN_2)O_2

Tobias Dierkes; Markus Str?bele; H. -Jürgen Meyer

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Between Oxoborate and Nitridoborate:The Oxonitridoborate Oxide La_3(OBN_2)O_2

机译：在草酸硼酸酯和三硼酸硼酸酯之间：氧化三苯硼酸镧La_3（OBN_2）O_2

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The new compound La_3(OBN_2)O_2 was prepared by a solid state reaction of LaOCl and Li_3(BN_2) at 1200 ℃ in a fused niobium ampoule. A single crystal structure refinement [Pnma, Z = 4, a = 1269.8(2) pm, b = 368.94(5) pm, c = 1101.1(2) pm] indicates the presence of a planar (OBN_2)~(5-) ion, which is structurally related to the (BN_3)~(6-) ion. The arrangement of atoms in the structure corresponds to a slightly modified structure of Ca_3(CBN)Cl_2 [Pnma, Z = 4, a = 1386.7(9) pm, b = 384.7(3) pm, c = 1124.7(6) pm].

机译：通过在熔融铌安瓿中于1200℃下进行LaOCl和Li_3（BN_2）的固态反应，制备了新的化合物La_3（OBN_2）O_2。单晶结构细化[Pnma，Z = 4，a = 1269.8（2）pm，b = 368.94（5）pm，c = 1101.1（2）pm]表示存在平面（OBN_2）〜（5-）在结构上与（BN_3）〜（6-）离子有关的离子。结构中原子的排列对应于Ca_3（CBN）Cl_2的稍微修饰的结构[Pnma，Z = 4，a = 1386.7（9）pm，b = 384.7（3）pm，c = 1124.7（6）pm] 。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2014年第7期|共5页
作者
Tobias Dierkes; Markus Str?bele; H. -Jürgen Meyer;
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正文语种 eng
中图分类化学;
关键词
Oxonitridoborate; Lanthanum; Crystal structure;

机译：三苯硼酸;镧;晶体结构;

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1. Between Oxoborate and Nitridoborate:The Oxonitridoborate Oxide La_3(OBN_2)O_2 [J] . Tobias Dierkes, Markus Str?bele, H. -Jürgen Meyer Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第7期

机译：在草酸硼酸酯和三硼酸硼酸酯之间：氧化三苯硼酸镧La_3（OBN_2）O_2
2. Conjugated Heterogeneous-Homogeneous Oxidations of Hydrogen in High-Density H_2/O_2/H_2O, H_2/O_2/CO_2, and H_2/O_2/N_2 Mixtures [J] . Russian journal of physical chemistry, B. . 2019,第8期

机译：高密度H_2 / O_2 / H_2O，H_2 / O_2 / CO_2和H_2 / O_2 / N_2混合物中的氢中氢的共轭非均相 - 均匀氧化
3. The [BN2]3? anion – a carbon dioxide isosteric building unit for a large family of complex nitridoborate structures [J] . RainerP?ttgen, OlafReckeweg Zeitschrift fur Kristallographie. Crystalline Materials . 2017,第10期

机译：[bn2] 3？阴离子 - 一种用于大型复合物硝基硼酸盐结构的二氧化碳制骨构建装置
4. Comparison of Chemical Vapor Deposited Hafnium Dioxide and Silicon Doped Hafnium Dioxide using either O_2, N_2O, H_2O, O_2 plasma, or N_2O plasma, and Hf (IV) t-butoxide [C] . Harish B. Bhandari, Ping Cheri, Tonya M. Klein Symposium Proceedings vol.811; Symposium on Integration of Advanced Micro- and Nanoelectronic Devices - Critical Issues and Solutions; 20040413-16; San Francisco,CA(US) . 2004

机译：使用O_2，N_2O，H_2O，O_2等离子体或N_2O等离子体和Hf（IV）叔丁醇对化学气相沉积二氧化Ha和掺杂二氧化Silicon的比较
5. Refinement of the crystal structures of praseodymium- and samarium-oxoborate-bis(oxophosphate)-oxide, Ln₇O₆[BO₃][PO₄]₂, (Ln = Pr, Sm) [O] . Ewald, B., Prots, Y., Kniep, R. 2004

机译：精制镨 - 和钐 - 氧代硼酸盐 - 双（氧代磷酸） - 氧化物，Ln _{7 O _{6 [BO _{3 ]的晶体结构[ pO _{4 ] _{2 ，（Ln = pr，sm）}}}}}

Between Oxoborate and Nitridoborate:The Oxonitridoborate Oxide La_3(OBN_2)O_2

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