A tetranuclear manganese cluster with a star-shaped Mn4O6 core motif: Directed synthesis using a mononuclear precursor complex

Reddig N.; Triller MU.; Pursche D.; Rompel A.; Krebs B.

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A tetranuclear manganese cluster with a star-shaped Mn4O6 core motif: Directed synthesis using a mononuclear precursor complex

机译：具有星形Mn4O6核心基序的四核锰簇：使用单核前体配合物进行定向合成

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The tetranuclear manganese(II) complex [Mn-4(PPi)(6)](BPh4)(2) (2) (Hppi = 2-pyridylmethyl-2-hydroxyphenylimine) is prepared by using the precursor complex [Mn(PPi)(2)]-H2O (1). Based on UV/Vis- and IR-spectroscopy data in combination with mass spectrometry it has been concluded that I is a mononuclear neutral Mn-II complex, in which two ppi ligands chelate the manganese atom. Compound 2 crystallizes in the tri-clinic space group P (1) over bar (no. 2), with a = 17.500(3), b = 17.955(4), c = 19.101(4) Angstrom, alpha = 113.79(3)degrees, beta = 111.33(3)degrees, gamma = 93.91(3)degrees, V = 4950(2) Angstrom(3) and Z = 2. In the tetranuclear [Mn-4(PPi)(6)](2+) compplex cation Mn(l), Mn(2), and Mn(3) are equivalently coordinated by two deprotonated Hppi ligands leading to a N4O2 donor set. The environment of the central Mn(4) is formed by coordination of three [Mn(PPi)(2)] fragments resulting in a phenoxo bridged star-shaped Mn4O6 core motif. The average distance of directly adjacent manganese ions is 3.310 Angstrom, whereas the average distance of Mn(1), Mn(2), and Mn(3) among each other is 5.732 Angstrom. [References: 31]

机译：四核锰（II）配合物[Mn-4（PPi）（6）]（BPh4）（2）（2）（Hppi = 2-吡啶基甲基-2-羟基苯基亚胺）通过使用前体配合物[Mn（PPi）（2）]-H 2 O（1）。基于UV / Vis和IR光谱数据并结合质谱，可以得出结论：I是单核中性Mn-II络合物，其中两个ppi配体螯合锰原子。化合物2在bar（2号）的三斜空间群P（1）中结晶，a = 17.500（3），b = 17.955（4），c = 19.101（4）埃，alpha = 113.79（3）度，β= 111.33（3）度，伽马= 93.91（3）度，V = 4950（2）埃（3），Z =2。在四核[Mn-4（PPi）（6）]（2 +）复合阳离子Mn（1），Mn（2）和Mn（3）由两个去质子化的Hppi配体等效配位，形成N4O2供体。中央Mn（4）的环境是通过三个[Mn（PPi）（2）]片段的配位形成的，从而形成一个苯氧桥式星形Mn4O6核心图案。直接相邻的锰离子的平均距离为3.310埃，而Mn（1），Mn（2）和Mn（3）之间的平均距离为5.732埃。 [参考：31]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2002年第11期|共5页
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Reddig N.; Triller MU.; Pursche D.; Rompel A.; Krebs B.;
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正文语种 eng
中图分类化学;
关键词
Manganese; Mn4o6 core; Precursor; Phenoxo bridge; Crystal-structure; Phanerochaete-chrysosporium; Lactobacillus-plantarum; Iron(iii) complex; Photosystem-ii; Pseudocatalase; Resolution; Reactivity; Peroxidase; Oxidation;

机译：锰;Mn4o6核;前驱体;酚醛桥;晶体结构;超细木耳-Chrysosporium;植物乳杆菌;铁（iii）络合物;光系统ii;假过氧化氢酶;拆分;反应性;过氧化物酶;氧化;

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1. A tetranuclear manganese cluster with a star-shaped Mn4O6 core motif: Directed synthesis using a mononuclear precursor complex [J] . Reddig N., Triller MU., Pursche D., Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第11期

机译：具有星形Mn4O6核心基序的四核锰簇：使用单核前体配合物进行定向合成
2. Mononuclear manganese(III) complexes as building blocks for the design of trinuclear manganese clusters: Study of the ligand influence on the magnetic properties of the [Mn-3(mu(3)-O)](7+) core [J] . Viciano-Chumillas M, Tanase S, Mutikainen I, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第13期

机译：单核锰（III）配合物作为三核锰簇设计的基础：配体对[Mn-3（mu（3）-O）]（7+）磁性能的影响
3. Synthesis of Trinuclear, Dinuclear and Mononuclear Carbamato-Zinc Complexes from Tetranuclear Precursors: A Top-Down Synthetic Approach to New Carbamates [J] . Dan Domide, Christiane Neuhauser, Elisabeth Kaifer, European journal of inorganic chemistry . 2009,第14期

机译：从四核前体合成三核，双核和单核氨基甲酸酯-锌配合物：自上而下的合成方法，新的氨基甲酸酯。
4. RECONSTITUTION OF THE WATER-OXIDIZING COMPLEX IN MANGANESE-DEPLETED PHOTOSYSTEM II PREPARATIONS USING MONONUCLEAR MANGANESE COMPLEXES [C] . Shuqin Li, Guangye Han, Guiying Chen, International Congress of Photosynthesis . 2005

机译：用单核锰配合物重建锰耗尽的光系统II制剂的水 - 氧化复合物
5. The synthesis and characterization of mononuclear manganese(II), dinuclear manganese(III) and copper(II) complexes. [D] . Yisgedu, Teshome Beyene. 2001

机译：单核锰（II），双核锰（III）和铜（II）配合物的合成与表征。
6. Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn–OH2/OH Motifs Relevant to H2O Activation by the Oxygen Evolving Complex in Photosystem II [O] . Christopher J. Reed, Theodor Agapie -1

机译：Mn-OH2 / OH母题与光系统中氧演化复合物激活H2O有关的四核簇中质子和电子转移的热力学
7. The Ligand Environment of the S2 State of Photosystem Ii: A Study of the Hyperfine Interactions of the Tetranuclear Manganese Cluster by 2D Hyscore Spectroscopy.‡ [O] . Lakshmi K.V., Milikisiyants Sergey, Chatterjee Ruchira, 2010

机译：光系统Ii S2状态的配体环境：通过二维Hyscore光谱学研究四核锰簇的超精细相互作用。‡

A tetranuclear manganese cluster with a star-shaped Mn4O6 core motif: Directed synthesis using a mononuclear precursor complex

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